日本地球惑星科学連合2014年大会

講演情報

ポスター発表

セッション記号 S (固体地球科学) » S-IT 地球内部科学・地球惑星テクトニクス

[S-IT40_1PO1] 地殻流体:その分布と変動現象への役割

2014年5月1日(木) 18:15 〜 19:30 3階ポスター会場 (3F)

コンビーナ:*中村 美千彦(東北大学大学院理学研究科地学専攻地球惑星物質科学講座)、佐久間 博(東京工業大学大学院理工学研究科地球惑星科学専攻)、市來 雅啓(東北大学大学院理学研究科)、高橋 努(独立行政法人海洋研究開発機構 地球内部ダイナミクス領域)

18:15 〜 19:30

[SIT40-P10] 高精度ホウ素同位体比迅速分析法の地下水・火山岩への応用

*谷水 雅治1永石 一弥2石川 剛志1 (1.海洋研究開発機構高知コア研究所、2.マリンワークジャパン)

Boron isotope ratio is a powerful tracer in the fields of geochemistry, biochemistry, and environmental chemistry. Boron isotope ratios are determined by TIMS or MC-ICP-MS with precisions of better than 0.1 % RSD, but a large inter-lab discrepancy of 0.6 % is still observed for actual carbonate samples (Foster, 2008). Here, we are trying to determine B isotope ratio by MC-ICP-MS with a simple and common analytical techniques using a quartz sample introduction system with a PFA nebulizer, and compared to recently developed precise B isotope ratio analysis techniques by TIMS in positive ion detection mode determined as Cs2BO2+ ions with sample amount of <100 ng (Ishikawa and Nagaishi, 2011) and by MC-ICP-MS (Foster, 2008, Louvat et al., 2011).
In this year, our developed B analytical method above for carbonate and water samples are applied to rock samples. Resultant analytical reproducibility (twice standard deviation) was +/-0.04 % with a consumption of 50 ng B for several geochemical reference rocks issued from GSJ. Their relative differences from the standard were consistent with those determined by the positive TIMS within analytical uncertainty. Current potential B isotopic analysis by MC-ICP-MS will be discussed.