[1F01-04] Polymer, oligomer(1)

[1F01] Synthesis of Bottle Brush Polymers by Stereospecific Ring Opening Metathesis Polymerization using (Arylimido)vanadium-Alkylidene Catalysts

○Sirilak Mekcham¹, KOTOHIRO NOMURA¹ (1. Tokyo Metropolitan University)

In this presentation, we wish to introduce synthesis of new bottle brush polymers by stereospecific ring opening metathesis polymerization using (arylimido)vanadium-alkylidene catalysts. In particular, we succeeded synthesis in all cis and trans rich ROMP polymers by the ligand modification.

Keywords:polymerization, vanadium catalysts, bottle brush polymers