The 9th International Conference on Multiscale Materials Modeling

講演情報

Symposium

H. Multiscale Mechanics of Polymers, Soft Matter and Network Materials

[SY-H2] Symposium H-2

2018年10月30日(火) 11:15 〜 12:30 Room9

Chair: Hansohl Cho(Los Alamos National Laboratory, United States of America)

[SY-H2] Hydrogels with Dynamic Sacrificial Bonds - From Toughness to Adhesion to Composites -

Invited

Jian Ping Gong1,2 (1.Faculty of Advanced Life Science, Hokkaido University, Japan, 2.Soft Matter GI-CoRE, Hokkaido University, Japan)

Invention of the tough double network hydrogels (DN gels), consisting of interpenetrated rigid/brittle network and soft/stretchable network, shows that the effective energy dissipation by the breaking of the covalent bond of the brittle network prevents catastrophic crack propagation upon deformation, and thus, gives the extraordinarily high toughness of the material. Such sacrificial bond effect has been successfully applied to develop tough double network hydrogels of diverse chemistry and also to double and triple network elastomer materials. Thus, sacrificial bond concept is proved to be a general approach for developing tough soft materials. As the internal rupture of DN gels is due to the irreversible breaking of the covalent bonds of the brittle network, the conventional DN gels deteriorate gradually after repeated deformation. To address this problem, many recent works have replaced the covalent bonds with non-covalent bonds to allow the sacrificial bonds to be reformed. In this talk, novel hydrogels with reversible sacrificial bonds developed in author’s group are reviewed and their excellent mechanical behaviors such as high toughness, self-healing, adhesion to biological tissues, and fast underwater adhesion are demonstrated. Furthermore, this principle is extended to develop tough composites using tough hydrogels as energy dissipative soft matrix.