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[17F-T15-07] Fabrication of Bulk High-Temperature δ-MoC Phase by Mechanical Alloying and Subsequent Pulsed Current Sintering, and Investigation of Its Several Properties
Keywords:hardness, thermal conductivity, electrical resistivity, NaCl structure
The Ti doped high temperature δ-MoC phase was fabricated by mechanical alloying and subsequent pulsed current sintering. The sample with the composition of (Mo(1-x)Tix)60C40, x = 0.1 – 0.5, exhibited the δ-MoC structure (NaCl structure). In contrast, sample with x = 0 had a hexagonal Mo2C and AsTi structured MoC0.5 phases. The electrical resistivity increased with Ti content of x = 0.1 - 0.5. The thermal conductivities of the samples increased with increasing temperature ranging in 303 K - 553 K. The values at 303 K were 7 - 9 W (m K)-1 in the sample with x = 0.1 - 0.5, these values were smaller than those of TiC and WC.