日本地球惑星科学連合2015年大会

講演情報

インターナショナルセッション(口頭発表)

セッション記号 M (領域外・複数領域) » M-IS ジョイント

[M-IS03] Exploring the role of soil in earth science: ecological/biogeochemical linkage and beyond

2015年5月27日(水) 11:00 〜 12:45 104 (1F)

コンビーナ:*和穎 朗太(農業環境技術研究所 物質循環研究領域)、小崎 隆(首都大学東京)、座長:和穎 朗太(農業環境技術研究所 物質循環研究領域)

12:30 〜 12:33

[MIS03-P09] サブミクロスケールで起こる有機物と鉱物の相互作用の可視化

ポスター講演3分口頭発表枠

*浅野 眞希1和穎 朗太2武市 泰男3前田 誠4菅 大暉5山口 紀子2平舘 俊太郎2高橋 嘉夫5 (1.筑波大学、2.(独)農業環境技術研究所、3.高エネルギー加速器研究所、4.広島大学、5.東京大学)

キーワード:土壌有機物, 土壌団粒, 非晶質鉱物, 火山灰土壌, STXM

Soil organic matter (SOM) accounts for a major portion of terrestrial C and is considered to be stabilized against microbial degradation due partly to its interaction with soil minerals. Significant control of poorly-crystalline mineral phases on soil organic matter turnover as well as its storage has been shown based on field correlation studies and incubation experiments. Yet how organic compounds of microbial and plant origins interact with poorly-crystalline and other mineral phases within soil aggregate structure at the spatial scale relevant to microbial extracellular enzymes (tens of nanometers) remain unclear. Here we focused on the sonication-resistant particles that are enriched in organic matter (OM) from an Andisol, the soil order characterized by high contents of OM and poorly-crystalline minerals and high aggregate stability, and tested the hypothesis that submicron-scale OM distribution within a soil particle is controlled by poorly-crystalline minerals using scanning transmission X-ray microscopy (STXM) and near-edge X-ray absorption fine structure (NEXAFS) as well as scanning and transmission electron microscopy (SEM, TEM). We will demonstrate that the combination of synchrotron and other spectroscopic techniques used here is a powerful approach to directly examine soil organo-mineral associations occurring at submicron scale, which can contribute to enhance our mechanistic understanding of SOM stabilization processes.