[2I05-09] Radiolysis

[2I08] Radiolysis of Aqueous Solution of NaCl

Pulse Radiolysis Experiment and Spur Model Simulation.

*Shinichi Yamashita Yamashita¹, Kuniki Hata², Yusa Muroya³, Yosuke Katsumura⁴ (1. The University of Tokyo, 2. JAEA, 3. Osaka University, 4. JRIA)

Keywords:radiolysis, seawater, primary yield, spur process, chloride, oxoacid, corrosion

We have been investigating on radiolysis of aqueous solution of sodium chloride, one of the major solutes of seawater, especially at early stage within a microsecond. Concentration of chloride anion is 0.6 M in seawater, and such high concentration could change initial process within a microsecond, namely spur process. Change of spur process results in different primary yields after spur process, leading to difference in long-term quantitative estimation of subsequent production of stable products. We will show our recent activities: pulse radiolysis experiment to observe fast reactions and theoretical consideration using spur model simulation.