Academic Program (AP)

Organic Chemistry -Reaction and Synthesis- Organometallic Compounds

Mon. Mar 23, 2020 12:40 PM - 5:40 PM H8 (K610, Lecture Hall Bldg. [6F])

2H8-23～2H8-28 MUTOH, Yuichiro
2H8-31～2H8-36 ASAKO, Sobi
2H8-39～2H8-45 SUZUKI, Itaru
2H8-47～2H8-52 NAGAE, Haruki

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12:40 PM - 12:50 PM

[2H8-23] Ruthenium-Catalyzed Enantioselective Propargylic Reduction of Propargylic Alcohols with Hantzsch Esters

Oral A

○DING, Haowei; NAKAJIMA, Kazunari; SAKATA, Ken; NISHIBAYASHI, Yoshiaki (Fac. Eng., The Univ. of Tokyo)

PC Setting Time: 12:30-12:40

12:50 PM - 1:10 PM

[2H8-24] Ruthenium-Catalyzed Enantioselective Propargylic Substitution Reactions with Phosphine Oxides

Oral B

○LIU, Shiyao; TANABE, Yoshiaki; KURIYAMA, Shogo; SAKATA, Ken; NISHIBAYASHI, Yoshiaki (Grad. Sch. Eng., The Univ. of Tokyo)

PC Setting Time: 12:30-12:40

1:10 PM - 1:20 PM

[2H8-26] Degradation of β-O-4 Linkage by Cyclopentadienone Metal Complexes

Oral A

○KISHINO, Masamichi; KUSUMOTO, Shuhei; NOZAKI, Kyoko (Grad. Sch. Eng., The Univ. of Tokyo)

PC Setting Time: 12:30-12:40

1:20 PM - 1:30 PM

[2H8-27] Cobalt-Catalyzed Double [2 + 2 + 2] Cycloaddition for Trimerization of α,ω-Diynes

Oral A

○NAKAMURA, Koji; NAKATSUKA, Hitoshi; OGIWARA, Yohei; SAKAI, Norio (Fac. Sci. Technol., TUS)

PC Setting Time: 12:30-12:40

1:30 PM - 1:50 PM

[2H8-28] (E)-Selective Cross-dimerization of Terminal Alkynes Catalyzed by a Cobalt Complex with a Sterically Demanding Phenanthroline Ligand

Oral B

○UEDA, Yohei; TSURUGI, Hayato; MASHIMA, Kazushi (Grad. Sch. Eng. Sci., Osaka Univ.)

PC Setting Time: 12:30-12:40

2:00 PM - 2:10 PM

[2H8-31] Additive Effects of Potassium Alkoxides for Transesterification Catalyzed by Manganese Complexes

Oral A

○AKEBI, Shin-ya; KATO, Daiki; HIRAI, Takahiro; NAGAE, Haruki; MASHIMA, Kazushi (Grad. Sch. Eng. Sci., Osaka Univ.)

PC Setting Time: 13:50-14:00

2:10 PM - 2:20 PM

[2H8-32] Substrate Scope for The Esterification of Aliphatic Amides by Manganese-Potassium Catalyst

Oral A

○KATAYAMA, Shoichiro; HIRAI, Takahiro; KATO, Daiki; MAI, Binh Khanh; NAGAE, Haruki; HIMO, Fahmi; MASHIMA, Kazushi (Grad. Sch. Eng. Sci., Osaka Univ.)

PC Setting Time: 13:50-14:00

2:20 PM - 2:40 PM

[2H8-33] Mechanistic study on The Esterification of Tertiary Amides Mediated by Manganese-Potassium Catalysis

Oral B

○HIRAI, Takahiro; KATO, Daiki; MAI, Binh Khanh; KATAYAMA, Shoichiro; NAGAE, Haruki; HIMO, Fahmi; MASHIMA, Kazushi (Grad. Sch. Eng. Sci., Osaka Univ.)

PC Setting Time: 13:50-14:00

2:40 PM - 2:50 PM

[2H8-35] Manganese-catalyzed C(sp³)-H Bromination

Oral A

○SNEH, Kumar; TORIGOE, Takeru; KUNINOBU, Yoichiro (Grad. Sch. Eng. Sci., Kyushu Univ.)

PC Setting Time: 13:50-14:00

2:50 PM - 3:10 PM

[2H8-36] Scandium-Catalyzed Diastereoselective [3+2] Annulation of Aldimines with Alkenes via sp³ C－H Activation

Oral B

○CONG, Xuefeng; HOU, Zhaomin (RIKEN CSRS)

PC Setting Time: 13:50-14:00

3:20 PM - 3:40 PM

[2H8-39] Experimental and Theoretical Studies on Regiodivergent C-H Alkylation of Quinolines with Alkenes by Rare-Earth Catalysts

Oral B

○LOU, Shaojie; NISHIURA, Masayoshi; HOU, Zhaomin (RIKEN CSRS)

PC Setting Time: 15:10-15:20

3:40 PM - 3:50 PM

[2H8-41] Structural Determination of Allylgermanes and the Effects of the Coordination Structure on the Reactivity of Allylgermanes

Oral A

○MINAMI, Yohei; NISHIDA, Kento; KONISHI, Akihito; YASUDA, Makoto (Grad. Sch. Eng., Osaka Univ.)

PC Setting Time: 15:10-15:20

3:50 PM - 4:00 PM

[2H8-42] Group 16 Element Introduction Reactions to Germanium(II) Center of a Stable Germylene Bearing TbtCH₂ Group

Oral A

○YUKIMOTO, Mariko; TOKITOH, Norihiro (ICR, Kyoto Univ.)

PC Setting Time: 15:10-15:20

4:00 PM - 4:10 PM

[2H8-43] Synthesis of Phosphino-substituted Pheox-aluminum Complexes and Their Application to Catalysts for Regioselective Cycloaddition Reaction

Oral A

NISHIMOTO, Yoshihiro; ○KIDO, Kazuki; YASUDA, Makoto (Grad. Sch. Eng., Osaka Univ.)

PC Setting Time: 15:10-15:20

4:10 PM - 4:20 PM

[2H8-44] Rhenium-catalyzed Selective Synthesis of Two Kinds of Products from ο-Ethynylphenyl Carbonyl Compounds and Elecron-rich Alkenes

Oral A

○TAKANO, Takuto; IWASAWA, Nobuharu (Sch. Sci., Tokyo Tech.)

PC Setting Time: 15:10-15:20

4:20 PM - 4:30 PM

[2H8-45] Rhenium-Catalyzed Oxidative Cyclization of ω-Alkynylamides with Pyridine N-oxides as Oxidants Leading to Cyclic Imides

Oral A

FUKUMOTO, Yoshiya; ○MONDA, Shizuki; TAKAMI, Yasuhiro; CHATANI, Naoto (Grad. Sch. Eng., Osaka Univ.)

PC Setting Time: 15:10-15:20

4:40 PM - 5:00 PM

[2H8-47] Mechanistic study of indium-catalyzed C-F bond transformation: New synthetic strategy of fluorinated heterocycles

Oral B

○YATA, Tetsuji; NISHIMOTO, Yoshihiro; CHIBA, Kouji; YASUDA, Makoto (Grad. Sch. Eng., Osaka Univ.)

PC Setting Time: 16:30-16:40

5:00 PM - 5:10 PM

[2H8-49] InI₃-Catalyzed Synthesis of Unprotected N-Heterocycles via the Addition of Silyl Enorates into 2H-azirines

Oral A

○TAKENAKA, Yuya; SHIBATA, Ikuya; SUZUKI, Itaru (Grad. Sch. Eng., Osaka Univ.)

PC Setting Time: 16:30-16:40

5:10 PM - 5:20 PM

[2H8-50] Catalytic Synthesis of Oxaspiro Rings by Annulation of Methylenecyclopropanes with Benzoyl Cyanoalkenes via Intramolecular Oxa-Michael Addition of Enolates

Oral A

○OGURA, Kazuki; SUZUKI, Itaru; SHIBATA, Ikuya (Grad. Sch. Eng., Osaka Univ.)

PC Setting Time: 16:30-16:40

5:20 PM - 5:30 PM

[2H8-51] Base-Promoted Stannylative Substitution of Aryl Halides with Silylstannanes

Oral A

○HIRAOKA, Yuta; OSAKA, Itaru; YOSHIDA, Hiroto (Grad. Sch. Eng., Hiroshima Univ.)

PC Setting Time: 16:30-16:40

5:30 PM - 5:40 PM

[2H8-52] Binary Remote 1,5-Asymmetric Induction from Allyltin Reagent Containing Phosphate Ester and Its Application to Natural Product Synthesis

Oral A

○HAYAMI, Kuniyuki; NISHIGAICHI, Yutaka (Grad. Sch. Nat. Sci. & Tech., Shimane Univ.)

PC Setting Time: 16:30-16:40

Session information

Organic Chemistry -Reaction and Synthesis- Organometallic Compounds

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