Experimental verification of stereocontrol mechanism of entropy-dependent asymmetric aza-Friedel-Crafts reaction using guanidine-bisthiourea organocatalyst

○KAWAGUCHI

Presentation information

Academic Program (AP)

Organic Chemistry -Reaction and Synthesis- Aliphatic and Alicyclic Compounds

Wed. Mar 21, 2018 9:00 AM - 11:10 AM H4 (1141, Bldg. 11)

2H4-01～2H4-06　KUWANO, Satoru
2H4-08～2H4-11　AMII, Hideki

10:10 AM - 10:20 AM

[2H4-08] Experimental verification of stereocontrol mechanism of entropy-dependent asymmetric aza-Friedel-Crafts reaction using guanidine-bisthiourea organocatalyst

01.Oral A

○KAWAGUCHI, Masaki; NAKANO, Katsuhiro; HOSOYA, Keisuke; ODAGI, Minami; YAMANAKA, Masahiro; NAGASAWA, Kazuo (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Coll. Sci., Rikkyo Univ.)

PC Setting Time : 10:00 - 10:10

Keywords:organocatalyst、guanidine-bisthiourea、asymmetric aza-Friedel-Crafts reaction、entropy-dependent stereocontrol