Asymmetric Direct Alkynylation of α-Ketoesters with Terminal Alkynes Catalyzed by Chiral Prolinol-Phosphine-Copper Complexes

○FUJIOKA

Presentation information

Academic Program (AP)

Organic Chemistry -Reaction and Synthesis- Organometallic Compounds

Thu. Mar 22, 2018 1:40 PM - 6:30 PM H1 (1131, Bldg. 11)

3H1-29～3H1-34　ENDOU, Kouhei
3H1-36～3H1-41　OKAMOTO, Kazuhiro
3H1-43～3H1-49　OOHASHI, Masato
3H1-51～3H1-57　OKUDA, Yasuhiro

3:20 PM - 3:30 PM

[3H1-39] Asymmetric Direct Alkynylation of α-Ketoesters with Terminal Alkynes Catalyzed by Chiral Prolinol-Phosphine-Copper Complexes

01.Oral A

○FUJIOKA, Akane; SCHWARZER C., Martin; ISHII, Takaoki; OHMIYA, Hirohisa; MORI, Seiji; SAWAMURA, Masaya (Fac. Sci., Hokkaido Univ.; Coll. Sci., Ibaraki Univ.; Grad. Sch. Med. Sci., Kanazawa Univ.)

PC Setting Time : 14:40 - 14:50

Keywords:Copper、Alkynylation、Cooperative catalyst、α-Ketoesters、Tertiary propargylic alcohols