Acid-catalyzed Chirality-transferring Intramolecular Friedel-Crafts Reaction of α-Hydroxy-α-alkenylsilanes

○KUBOTA

Presentation information

Academic Program (AP)

Organic Chemistry -Reaction and Synthesis- Aliphatic and Alicyclic Compounds

Fri. Mar 23, 2018 9:00 AM - 12:20 PM H4 (1141, Bldg. 11)

4H4-01～4H4-06　HORIBE, Takahiro
4H4-08～4H4-13　ASANO, Keisuke
4H4-15～4H4-20　KIYOKAWA, Kensuke

11:40 AM - 11:50 AM

[4H4-17] Acid-catalyzed Chirality-transferring Intramolecular Friedel-Crafts Reaction of α-Hydroxy-α-alkenylsilanes

01.Oral A

○KUBOTA, Shunnichi; AKAGI, Wataru; IKEDA, Naoko; HIGASHINO, Masato; SHINADA, Teturo; OHUNE, Yasuhumi; NISHIMURA, Takahiro; SAKAGUCHI, Kazuhiko (Grad. Sch. Sci., Osaka City Univ.)

PC Setting Time : 11:10 - 11:20

Keywords:α-hydroxy-α-alkenylsilanes、Friedel-Crafts reaction、chirality transfer、α-silyl cation、acid catalyst