Enantioselective Friedel-Crafts Alkylation Reaction with non-activated β-Alkyl-β-Nitrostyrenes Catalyzed by Chiral BINOL Phosphates

○KANEKO

Presentation information

Academic Program (AP)

Organic Chemistry -Reaction and Synthesis- Aliphatic and Alicyclic Compounds

Sat. Mar 16, 2019 1:10 PM - 6:20 PM E6 (347, Bldg. 3 [4F])

1E6-26～1E6-31　YAMANAKA, Masahiro
1E6-33～1E6-38　MOMIYAMA, Norie
1E6-40～1E6-43　MIYAGAWA, Masamichi
1E6-46～1E6-50　ASANO, Keisuke
1E6-52～1E6-56　HATANO, Manabu

1:50 PM - 2:00 PM

[1E6-30] Enantioselective Friedel-Crafts Alkylation Reaction with non-activated β-Alkyl-β-Nitrostyrenes Catalyzed by Chiral BINOL Phosphates

Oral A

○KANEKO, Mio; IBÁÑEZ SÁNCHEZ, Ignacio; TAKAHIKO, Akiyama (Fac. Sci., Gakushuin Univ.)

PC Setting Time : 13:00 - 13:10

Keywords:Friedel-Crafts alkylation reaction、chiral metal BINOL bis(phosphate) complex、Lewis acid catalyst、all-carbon quaternary center

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