[A-AS22_1PO1] Atmospheric Chemistry

[AAS22-P24] Validation observation for the derivation of lower tropospheric ozone by remote sensing

*Fumiya YANAKA¹, Kazuyuki KITA², Yuuki YAMAGUCHI¹, Tabito FUKUJU¹, Ryohei ITABASHI¹, Takeshi KINASE¹, Hitoshi IRIE³, Katsuyuki NOGUCHI⁴, Tomoki NAKAYAMA⁵, Yutaka MATSUMI⁵, Tomohiro NAGAI⁶, Tetsu SAKAI⁶, Yuji ZAIZEN⁶, Isamu MORINO⁷, Osamu UCINO⁷, Makoto INOUE⁷, Tomoaki TANAKA⁸ (1.Graduate School of Science and Engineering, Ibaraki University, 2.College of Science, Ibaraki University, 3.Center for Environmental Remote Sensing, Chiba University, 4.Faculty of Science, Nara Women's University, 5.Solar-Terrestrial Environment Laboratory, Nagoya University, 6.Meteorological Research Institute, 7.National Institute for Environmental Studies, 8.NASA Ames Research Center)

Keywords:Remote Sensing, Lower tropospheric ozone

The lower tropospheric ozone is a major component of photochemical oxidant which causes photochemical smog, adversely affecting human health and vegetation when it comes to high concentration. Therefore knowing their behavior as air pollution is an important. In recent years, contrary to the reduction of lower tropospheric ozone precursor gases, their amount is increasing. It has been suggested that the long-range transport of the lower tropospheric ozone from Asian Continent affects air quality in Japan and other wide areas. Remote sensing from a satellite is effective to observe such extensive/transboundary air pollution. However it has been quite difficult to measure the lower tropospheric ozone from satellite. We have proposed that it can be evaluated with simultaneous measurement of solar backscattering spectra in the ultraviolet(UV) and visible(Vis) regions. Because the atmospheric Rayleigh scattering cross-section is much larger in UV than that in Vis, lower tropospheric light path length of the solar scattered radiation observed from space is significantly different in these two wavelength regions. This difference of light path enables us to detect the lower tropospheric ozone by the simultaneous measurement of UV and Vis solar backscattered spectra from space. For the validation of this technique, we carried out aircraft experiments to validate this method over Tsukuba on 10th and 13rd September 2012. UV and Vis backscatter spectra were measured with two spectroscopes (Maya2000pro, Ocean Optics, USA) at two altitudes 2500 ft (760 m) and 25000 ft (7600 m). Simultaneously, ozone profile was measured with ozone monitors on-board the aircraft, with ozonesonde launched near Tsukuba, and the tropopheric ozone lidar. Because aerosol scattering may significantly affect the evaluation of the lower tropospheric ozone amount, in situ aerosol observation with the CRDS, PSAP, and PASS instruments and the lidar observation were carried out in the Meteorological Research Institute. From the aircraft, we observed solar scattered radiation from zenith, nadir and 20 degree oblique directions in ultraviolet(300 - 380nm wavelength) and visible(400 - 700nm wavelength) spectral range. Because the surface reflected light greatly contribute to the scattered light from nadir, especially in the visible spectral range, for accurately estimation of the ozone amount, it is particularly important to understand the surface reflection spectrum. In this experiment, ground reflection spectra at different surface conditions such as rice paddy, forest, urban, farm areas and so on were measured at a low altitude of 2500ft (760m). It is necessary to consider the effect of scattering near the aircraft to estimate the surface reflected light. We estimated it with SCIATRAN (Rozanov et al., 2005). Results of these observations will be presented at this session.