*Hirofumi OHYAMA1, Yasuko ISONO1, Miku UEMURA1, Tomoo NAGAHAMA1, Akira MIZUNO1, Masaki TSUTSUMI2, Mitsumu EJIRI2, Takuji NAKAMURA2
(1.Solar-Terrestrial Environmental Laboratory, Nagoya University, 2.National Institute of Polar Research)
Keywords:ozone, nitric oxide, remote sensing
Precipitation of energetic particle into the atmosphere impacts abundances of atmospheric constituents in the middle atmosphere. Highly energetic solar protons, which directly enter the middle atmosphere, cause increase of HOx and NOx species. Energetic electrons also increase NOx in the thermosphere, and the downward transport in the polar vortex moves the produced NOx to lower altitudes. These NOx species cause a decrease of O3 in the middle atmosphere through catalytic reactions [Seppälä et al. 2006; Daae et al., 2012]. To investigate the effect of NOx on O3 variation in the polar region, a ground-based millimeter-wave spectroscopic radiometer was installed at Syowa Station, Antarctica in March 2011. The instrument has recorded brightness temperature spectra of rotational emission from the atmospheric O3 and NO molecules. From the NO spectra, both multiple short-term enhancements and seasonal variation of NO column are observed [Isono et al., 2014]. The short-term enhancements are correlated with the energetic particle precipitation. In the present study, O3 profiles are retrieved from the brightness temperature spectra between 238.94-239.24 GHz, whose spectral range has sensitivity to the O3 abundance between 20 and 70 km. The optimal estimation scheme is used for the O3 profile retrieval, along with radiative transfer calculation through the use of the NCEP reanalysis data and spectroscopic parameters. Since the O3 spectra are integrated over 1 hour every 6 hours, we usually derive four O3 profiles in a day. We present the result of O3 retrieval and discuss how the O3 mixing ratios at given altitudes response to the short-term NO column enhancement.