Japan Geoscience Union Meeting 2014

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Symbol S (Solid Earth Sciences) » S-GC Geochemistry

[S-GC56_30PO1] Solid Earth Geochemistry, Cosmochemistry

Wed. Apr 30, 2014 6:15 PM - 7:30 PM Poster (3F)

Convener:*Shimoda Gen(Geological Survey of Japan, AIST), Katsuhiko Suzuki(Institute for Research on Earth Evolution, Japan Agency for Marine-Earth Science and Technology), Katsuyuki Yamashita Katsuyuki(Graduate School of Natural Science and Technology, Okayama University)

6:15 PM - 7:30 PM

[SGC56-P01] Helium and halogen compositions in MORB vesicles

*Takanori KAGOSHIMA1, Naoto TAKAHATA1, Yuji SANO1 (1.Atmosphere and Ocean Research Institute, University of Tokyo)

Keywords:Mid-ocean ridge basalt, Helium, Halogen, Flux, Geochemical cycle

Degassing behavior of halogens through submarine volcanism is not well understood. We determined helium and halogen compositions of MORB vesicles to constrain halogen flux at ridges. Samples collected at 8 sites (13oN-17oS on EPR; 15oN-37oN on MAR; 24-25oS on CIR) were crushed in dilute NaOH or NH3 solution at liquid nitrogen temperature and volatiles were extracted from vesicles. Helium isotope compositions were determined with a VG-5400 MS and F and Cl contents were measured with ICS-2100 ion chromatography. For glass matrix, concentration of F and Cl were determined with a NanoSIMS.For vesicles, the average 3He concentration was (4.5+/-2.1)x10-15 mol/g of sample and the average F/3He and Cl/3He ratios were (1.4+/-0.5)x106 and (2.9+/-0.6)x107. This provides F and Cl flux of (7.1+/-2.8)x108 mol/y and (1.5+/-0.4)x1010 mol/y at ridges calibrating against the known 3He flux of 530 mol/y. They may be defined as lower limits of MOR flux because F and Cl contents in glass matrix are >7000 and >100 times higher than those in vesicles and dissolution of only a small part of volatiles staying in oceanic crust into the ocean will increase volatile flux significantly. The large difference between F/Cl ratios in vesicles and glass matrix reflects difference in vesicle/glass partition coefficients of these elements, which suggests that they have significantly different degassing behavior at ridges. From the data of the noble gas method on MORB in literature, Br/Cl and I/Cl ratios in vesicles were calculated to be (1.8+/-0.1)x10-3 and (5.4+/-0.1)x10-5 which are almost equivalent with those in glass matrix [1], suggesting their vesicle/glass partition coefficients are similar in submarine basaltic magma. Br and I flux at ridges were calculated to be (2.7+/-0.8)x107 mol/y and (8.3+/-2.4)x105 mol/y based on the Cl flux estimated in this study. They are the first estimate of Br and I flux obtained by indirect calibration against 3He flux and may be lower limits of MOR flux by the same reason as Cl. Combination of the method in this study and the noble gas method on the same sample will give us new insight into degassing behavior and geochemical cycles of halogens.Reference: [1] Kendrick et al. (2012) GCA 81, 82-93.