Japan Geoscience Union Meeting 2015

Presentation information


Symbol P (Space and Planetary Sciences) » P-PS Planetary Sciences

[P-PS24] Origin and evolution of materials in space

Wed. May 27, 2015 4:15 PM - 5:00 PM A02 (APA HOTEL&RESORT TOKYO BAY MAKUHARI)

Convener:*Shogo Tachibana(Department of Natural History Scieces, Hokkaido University), Hitoshi Miura(Graduate School of Natural Sciences, Department of Information and Biological Sciences, Nagoya City University), Takafumi Ootsubo(Graduate School of Arts and Sciences, University of Tokyo), Mitsuhiko Honda(Department of Mathematics and Physics, Kanagawa University), Chair:Hitoshi Miura(Graduate School of Natural Sciences, Department of Information and Biological Sciences, Nagoya City University)

4:15 PM - 4:30 PM

[PPS24-15] Reproduction experiment of molecular formation based on Fischer-Tropsh-type catalytic reaction in the early solar nebula

*Yuki KIMURA1, Tomoya YAMAZAKI1, Akira TSUCHIYAMA2, Hiroko NAGAHARA3, Tetsuya HAMA1, Hiroshi HIDAKA1, Naoki WATANABE1, Akira KOUCHI1 (1.Institute of Low Temperature Science, Hokkaido University, 2.Kyoto University, 3.The University of Tokyo)

Keywords:organics, catalytic reaction, molecular formation, low temperature science, solar nebula

Catalytic reactions such as the Fischer-Tropsch type and Haber-Bosch type reactions are able to produce organic molecules efficiently on the surface of cosmic dust analogues, such as iron, magnetite, amorphous iron silicate and graphite at temperature above 573 K and pressure at 105 Pa in the laboratory [1-4]. In these experiments, organic molecules ranging from methane (CH4), ethane (C2H6), benzene (C6H6) and toluene (C7H8), to more complex species such as acetone (C3H6O), methyl amine (CH3NH2), acetonitrile (CH3CN) and N-methyl methylene imine (H3CNCH2) have been produced so far. However, it is not obvious the reaction similarly works in the solar nebula and is able to extrapolate to the actual early nebula environment at lower temperature below 500 K and lower pressure under 102 Pa. Therefore, we developed a new experimental system to test the catalytic chemical reactions in the early nebula environment [lower temperature (100-500 K) and pressure (10-3-100 Pa)] using a substrate of magnesium silicate or iron. Our experimental system has a temperature-controlled substrate, a Fourier transform infrared spectrometer (FT-IR), and two quadrupole mass spectrometers (Q-MSs). FT-IR measures the vibration modes of adsorbed and produced molecules on the surface and the Q-MSs detect volatile molecules, respectively. As a preliminary experiment, the substrate of a magnesium silicate thin film was used in a continuous gas flow of a mixture gas of H2 and CO for Fischer-Tropsch type reactions. Unfortunately, however, we do not find any signal of the Fischer-Tropsch type reaction and resulting organic molecules on the amorphous magnesium substrate, whereas the signal of CHO molecule and ethane (C2H6) have been detected on the Q-MS spectra in some experimental condition on a different substrate. In the workshop, the detail results using iron substrate will be presented as a function of temperature and pressure.

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