[A-HW16] 流域生態系の水及び物質の輸送と循環－源流域から沿岸域まで－

[AHW16-06] 河川水および地下水中のクロロフルオロカーボン類を用いた盆地の地下水硝酸態窒素汚染源のトレースのためのフィージビリティスタディ

*中屋 眞司¹、青山 里輝² (1.信州大学工学部水環境・土木工学科、2.信州大学工学部土木工学科)

キーワード：地下水、クロロフルオロカーボン類、硝酸、地下水汚染

Chlorofluorocarbons CFC-12, CFC-11, CFC-113, which are primarily of anthropogenic origin, are often used to young groundwater dating. However, CFCs concentrations are extremely over record (EOR) in 40 % in sampling points of the well waters in Matsumoto basin as well as in other agricultural basin. The concentration of CFCs in EOR is also likely to increase with NO₃-N. Supposing CFCs with NO₃-N enrich along groundwater flow path, the source area of NO₃-N pollution can be identified by tracing the relationship between CFCs, NO₃-N and the location. In order to identify the source of NO₃-N in agricultural basin, we carried out feasibility study using CFCs. We measured the CFCs and SF₆ concentrations of river water at 19 points of three rivers, groundwater at 21 wells and air at 19 points along rivers in the Matsumoto basin. The CFCs’ concentrations of river waters exponentially increase with distance and elapsed time in the direction from upstream to downstream up to air values of CFCs’ concentrations, being close to average atmospheric CFCs’ concentrations of north hemisphere. It is natural that the gradual increases of CFCs concentrations in rivers with distance and elapsed time reflects the process of gaining equilibrium between water and air. Moreover, CFCs’ concentrations of river water at beginning point of mountain stream will correspond to the CFCs of spring, in our understanding. The NO₃-N of river waters decreases with distance and elapsed time in the direction from upstream, surrounding vegetable fields, to downstream, indicating dilution due to river water. On the contrary, the CFCs’ concentrations of groundwater increase with NO₃-N from upstream, surrounding vegetable fields, to downstream along groundwater flow path, suggests CFCs with NO₃-N enrich in the groundwater. The relationship between CFCs and NO₃-N of river water and groundwater along groundwater flow paths is plotted around a same line, indicating that the source area of NO₃-N pollution of groundwater is identified to be vegetable fields.