Japan Geoscience Union Meeting 2018

Presentation information

[EE] Poster

S (Solid Earth Sciences) » S-IT Science of the Earth's Interior & Tectonophysics

[S-IT25] Deep Carbon: Diamond formation and carbon speciation in Earth and planetary processes

Tue. May 22, 2018 1:45 PM - 3:15 PM Poster Hall (International Exhibition Hall7, Makuhari Messe)

convener:Eiji Ohtani(Department of Earth and Planetary Materials Science, Graduate School of Science, Tohoku University), Konstantin Litasov(V.S. Sobolev Institute of Geology and Mineralogy SB RAS), Hiroyuki Kagi(東京大学大学院理学系研究科附属地殻化学実験施設, 共同), Craig E Manning (University of California Los Angeles)

[SIT25-P01] Revision of the CaCO3–MgCO3 phase diagram at 3 and 6 GPa

Anton Shatskiy1, Ivan Podborodnikov2, Anton Arefiev2, Daniil Minin1, Artem Chanyshev1, *Konstantin Litasov1 (1.V.S. Sobolev Institute of Geology and Mineralogy SB RAS, Novosibirsk, Russia, 2.Novosibirsk State University, Novosibirsk, Russia)

Keywords:carbonate, mantle, high pressure, phase diagram

Subsolidus and melting relationships in the system CaCO3–MgCO3 have been reexamined using a Kawai-type multianvil apparatus at 3 and 6 GPa in graphite capsules (Fig.1). Phase boundaries were delineated according to the chemical composition of phases measured by electron microprobe in energy dispersive mode and identification of crystal phases by Raman spectroscopy (Shatskiy et al., 2018).
At 3 GPa, the dolomite-magnesite solvus intersects the melting loop at about 1250 °C, and the isothermal three-phase line so produced represents the peritectic reaction: dolomite (Ca# 43) = magnesite (Ca# 13) + liquid (Ca# 48), where Ca# = 100×Ca/(Ca+Mg). The melting loop for the CaCO3–MgCO3 join extends from 1515 °C (CaCO3) to 1515 °C (MgCO3) through a liquidus minimum at 1230 °C (near 53 mol% CaCO3). Starting from 1425 °C at £30 mol% CaCO3 in the system, the liquid quenches to dendritic carbonate and periclase and contains rounded voids, indicating an incongruent melting reaction: MgCO3 (magnesite) = MgO (in liquid) + CO2 (fluid and/or liquid).
At 6 GPa, aragonite + magnesite assemblage is stable up to 1000 °C. The reaction aragonite + magnesite = dolomite locates between 1000 and 1050 °C. The presence of dolomite splits the system into two partial binaries: aragonite + dolomite and dolomite + magnesite. The dolomite-magnesite solvus intersects the melting loop between 1400 and 1450 °C, and the isothermal three-phase line so produced represents the peritectic reaction: dolomite (Ca# 31) = magnesite (Ca# 21) + liquid (Ca# 57). The melting loop for the CaCO3–MgCO3 join extends from 1660 °C (CaCO3) to 1780 °C (MgCO3) through a liquidus minimum at 1400 °C and 62 mol% CaCO3.
The compositions of carbonate crystals and melts from the experiments in the carbonated eclogite (Yaxley and Brey 2004) and peridotite (Dalton and Presnall 1998) systems are consistent with the geometry of the CaCO3-MgCO3 melting loop at 3 and 6 GPa: Ca-dolomite melt coexists with Mg-calcite in eclogite and peridotite at 3 GPa and dolomite melt coexists with magnesite in peridotite at 6 GPa.
This work is financially supported by Russian Science Foundation (project No 14-17-00609-P).
References
Dalton, J.A., Presnall, D.C. (1998) Contrib. Mineral. Petrol., 131: 123-135.
Shatskiy, A., Podborodnikov, I.V., Arefiev, A.V., Minin, D.A., Chanyshev, A.D., Litasov, K.D. (2018) Amer. Mineral., 103(3), doi: 10.2138/am-2018-6277.
Yaxley, G.M., Brey, G.P., (2004) Contrib. Mineral. Petrol., 146: 606-619.

Fig. 1. Isobaric T-X diagrams for the system CaCO3-MgCO3 at 3 and 6 GPa. Arg – aragonite, Cal or Ca-Dol – Mg-bearing calcite or Ca-rich dolomite, Dol – dolomite, Mgs – magnesite, F – CO2 fluid, L – liquid. Open and grey circles indicate composition of solid phases and liquid. Grey numbers denote eutectic and peritectic compositions in mol% CaCO3.