日本地球惑星科学連合2019年大会

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[J] 口頭発表

セッション記号 P (宇宙惑星科学) » P-PS 惑星科学

[P-PS07] 太陽系物質進化

2019年5月27日(月) 10:45 〜 12:15 A02 (東京ベイ幕張ホール)

コンビーナ:癸生川 陽子(横浜国立大学 大学院工学研究院)、藤谷 渉(茨城大学 理学部)、小澤 信(東北大学大学院理学研究科地学専攻)、松本 恵(東北大学大学院)、座長:癸生川 陽子小澤 信

11:00 〜 11:15

[PPS07-14] Yamato 791198 CMコンドライト中の炭酸塩鉱物粒子内における酸素・炭素同位体比の不均一性と水質変成過程での同位体比の変化

*藤谷 渉1青木 佑斗1牛久保 孝行2橋爪 光1 (1.茨城大学 理学部、2.海洋研究開発機構 高知コア研究所)

キーワード:炭酸塩鉱物、炭素質コンドライト、酸素同位体、炭素同位体

Carbonate minerals are ubiquitous in CM chondrites and formed by aqueous alteration in their parent body [1]. Previous studies have revealed a large variation in C isotope ratios of CM carbonates with δ13C values ranging from ~20 to ~90 ‰ [e.g., 2,3]. However, the reason for this variability has remained poorly understood. Here, we conducted in-situ C- and O-isotope measurements by SIMS along crystal growth within single carbonate grains in Yamato 791198 (CM 2.4) to trace the change in δ13C values during aqueous alteration.

First, we obtained color CL images of seven calcite (CaCO3) grains with an FE-EPMA. Then, we measured O and C isotope ratios of the calcite grains with the CAMECA ims-1280HR. Typically, the isotope measurements were carried out on three different points for each calcite grain. Finally, we obtained quantitative chemical compositions and elemental maps of Mg, Si, Ca, Mn, and Fe of the calcite grains using the same FE-EPMA as that for the CL images.

All grain analysed exhibit a clear zoning of Mn, Mg, and Fe. The zoning is well correlated with CL images. The heterogeneous distribution of minor elements and CL intensity likely reflects the crystal growth of these grains.

The O isotope ratios of the calcite grains significantly vary with the δ18O values ranging from ~22 to ~38 ‰. The O isotope ratios plot on a single trend line in an O three-isotope plot with a slope of ~0.61, slightly steeper than the terrestrial fractionation line, reflecting a progressive O-isotope exchange between initially 16O-poor water and 16O-rich rock [4,5]. The δ18O values also vary within single calcite grains, demonstrating crystal growth from a relatively dark CL core to a red CL periphery.

The δ13C values of the calcite grains range from 17 to 32 ‰. This range is much smaller than that observed for different carbonate grains or bulk meteorite samples by previous studies. Especially, the δ13C variations within individual grains are only 4 ‰ at most except for one grain. Previous studies have suggested that the observed δ13C variation was produced by the Rayleigh-type isotopic fractionation by the escape of 13C-poor methane [2], or equilibrium isotopic fractionation reflecting variable formation temperatures of carbonates [3]. However, the small intra-grain δ13C variations associated with the large δ18O change observed in this study cannot be explained by such processes. Instead, here we propose that the δ13C values of dissolved carbon species in aqueous solutions were locally heterogeneous, and did not significantly change during carbonate formation.



References: [1] Brearley A. J. (2006) in Meteorites and the Early Solar System II, 587-624. [2] Guo W. and Eiler J. M. (2007) GCA, 71, 5565-5575. [3] Alexander C. M. O’D. et al. (2015) Meteoritics & Planet. Sci., 50, 810-833. [4] Clayton R. N. and Mayeda T. K. (1984) EPSL, 67, 151-161. [5] Fujiya W. (2018) EPSL, 481, 264-272.