11:00 AM - 1:00 PM
[HRE13-P05] Modification of sequential extraction method for better understanding of host phases in high grade Ni laterite ores
Keywords:Nickel, Chemical weathering, Ultramafic rock, Sequential extraction, Clay minerals
Best selective extraction of Ni for ion exchangeable as well as iron (hydr)oxides phases from the laterite and saprolite samples was achieved by using ammonium acetate and sodium dithionite/citrate (DCB method), respectively. Although DCB method was repeated three times to increase recovery of Fe from (hydr)oxides, subsequent analysis for the residual phases shows minimal dissolution of silicate phases for almost all the samples but lower saprolite samples from Petea Hill. The modified sequential extraction applied to the whole weathering profiles demonstrated that Ni was mainly present in the crystal structure of silicate minerals in the saprolite layers at both Petea Hill and Tagaung Taung. The results are consistent with previous XRD and EPMA analyses suggesting secondary serpentine and smectite as the primary host minerals for Ni in the saprolite layer at Petea Hill and Tagaung Taung, respectively [2, 3]. Extraction of ion exchangeable phases from saprolite samples at Tagaung Taung suggests that Mg2+ is the major interlayer cation in the smectite. Although these silicate minerals are the main Ni hosts in the saprolite layers at both weathering profiles, the sequential extraction results also suggest that significant fractions (up to ~20%) of Ni were hosted by low crystalline Fe oxides in the saprolite layers. This is supported by EXAFS spectra obtained from the lower saprolite samples where Ni is highly concentrated. These results imply that Fe oxides may also concentrate Ni in the saprolite layer and play important roles in the Ni enrichment processes in both deposits.
[1] Hall, G.E.M., Beer, V. R., and Hoashi, M. (1996) J. Geochem. Explor. 56, 59-78.
[2] Ito, A., Otake, T., Maulana, A., Sanematsu, K., Sufriadin, Sato, T. (2021) Resour. Geol. 71. 255-82.
[3] Murofushi, A., Otake, T., Sanematsu, K., Zay Ya, K., Ito, A., Kikuchi, R., and Sato, T. (2022) Miner. Deposita.