11:00 AM - 1:00 PM
[MIS17-P05] Formation of bright materials on Ceres with explosive cryovolcanic eruption of deep subsurface liquid brines.
Keywords:Ceres, carbonate, cryovolcano
Here, we examined the salt formation upon decompression of volatile-containing liquid brines based on laboratory experiments. Our experimental results suggested that alkalinization of liquid brines due to consequent degassing of dissolved CO2 upon rapid decompression can explain the formation of Na2CO3 from moderately alkaline brines (pH down to 10.0). Small amounts of NH4-bearing salts could be formed with Na2CO3 if the brine samples contain the highly levels of NH3 (e.g., ΣNH3/ΣCO2 > 1). Based on our results, we constrained the possible chemical compositions of liquid brine source of the bright materials on Ceres. We also evaluated the chemical evolution of deep oceanic water of Ceres using thermodynamic equilibrium models. The comparison of experimental results and model evaluations suggest that if the subsurface liquid brines originate from deep oceanic water generated by water-rock interactions with water-to-rock ratios less than ~1, Na2CO3 with small amounts of NH4-bearing salts in the bright materials can be explained with its explosive cryovolcanic eruption. Given the young surface age of the bright materials, our results support that Ceres may have maintained the deep subsurface liquid ocean until today.