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[MIS18-27] Cretaceous Paleoenvironmental changes across the Albian-Cenomanian boundary in high latitude Southern oceans
Keywords:Cretaceous, alkenones, Albian, Cenomanian, biomarkers
In the present study, DSDP Leg 36 Site 327, DSDP Leg 40 Site 364, ODP Leg 122 Site 763, IODP Exp.369 Sites U1513, U1514 were analyzed in order to estimate paleoenvironments through the Cretaceous Albian/Cenomanian boundary interval in southen high latitudes, focusing particularly on organic geochemistgry. Significance of this study is derived from two reasons: 1) it focuses on southern high latitudes. The paleoenvironmental information has been overlooked across the Albian/Cenomanian boundary interval; 2) it focuses on biomarkers, which has not been studied for this period.
Alkyl ketones with forty carbons and two or three unsaturation bonds (C40:2 Et and C40:3 Et alkenones, respectively) were detected from some samples from Sites U1513, U1514, and 763 updating the oldest of record of them in the southern oceans. Considering previous reports from the Northern Hemosphere, haptophyte group that biosynthesized C40 alkenones may have prevailed worldwide by late Albian. The index UK’40 (UK’40= C40:2 Et/(C40:2 Et + C40:3 Et)) was tentatively introduced to evaluate relative change of SST. Based on the index, overall decrease of SST was suggested through the studied interval of U1513. It was accompanied by gradual domination of the alkenones over other marine plankton biomarkers suggesting replacement of primary producer. Indices of terrestrial aridification (relative decline of perylene and increase of chain length of long-chain n-alkanes) also showed concordant increase with the marine transition.
In summary, the present study demonstrated that a biomarker approach is useful to discuss global and local paleoenvironmental changes in the mid Cretaceous Albian/Cenomanian boundary interval. This study and following researches will lead to a better understanding of the global environmental changes through the Albian/Cenomanian boundary transition and of the mechanism of OAE-1d development.