9:00 AM - 9:15 AM
[AOS23-01] Decadal-scale increases of anthropogenic CO2 in Antarctic Bottom Water of the Indian sector of the Southern Ocean
Keywords:Anthropogenic CO2, Antarctic Bottom Water (AABW), Southern Ocean
To elucidate how large AABW, defined as neutral density of gn >= 28.27 kg m-3, takes up antCO2, we examined decadal-scale increases of antCO2 (ΔantCO2) along a zonal section at nominal 62°S ranging from 30°E to 160°E in the Indian sector of the Southern Ocean. For the purpose, we used high-quality data for CO2-system and related properties collected about 17 years apart in 1994/1995 and 2012/2013. These data were obtained under international observation programs such as World Ocean Circulation Experiment and Global Ship-based Hydrographic Investigations Program. Form depth - longitude section of ΔantCO2, it was found that there was a clear contrast of distributions of ΔantCO2 in AABW between the eastern and western sides of the Kerguelen Plateau. That is, higher increases of > 5 mmol kg-1 were found in the eastern side, while lower increases or even decreases were found in the western side. In the eastern side, in contrast to previous studies, increases of antCO2 were largest (> 9.0 mmol kg-1) in the bottom water, i.e., AABW. The higher increases were especially conspicuous east of 110°E. Significant increases of anthCO2 in bottom and deep waters were detected through the section, although they became gradually reduced in magnitude and depth range westward from 110°E. Vertical distributions of ΔantCO2 showed significant positive correlations with decadal-scale changes in CFC-12 and with distributions of SF6, both of which can be used as a proxy of ocean circulation and ventilation, meaning that the distributions were mainly controlled by physical processes. Comparison of ΔantCO2 between calculation methods with and without total alkalinity presented differences of ΔantCO2 west of 50°E (the latter was smaller than the former). This may be related to decreases in production of particulate inorganic carbons in the Southern Ocean (Freeman and Lovenduski, 2015). The highest storage rate of antCO2 was estimated to be 1.1 ± 0.6 mol m-2 a-1 at longitudes 130°−160°E, which is a value integrated from surface to bottom layers of statistically-significant ΔantCO2. With this condition of integration, we believe that the value is conservative. West of the Kerguelen Plateau, the storage rate was 0.2 ± 0.1 mol m-2 a-1 at most. The contrast is due probably to differences of formation regions of AABW; west of 80°E (Kerguelen Plateau), the AABW consists mostly of Weddell Sea-origin water, while east of it, the AABW consists of both the Adélie coast- and Ross Sea-origin waters.
The above results highlight that processes for uptake and accumulation of antCO2 by the bottom water work well in the Indian sector of the Southern Ocean, at least, in the eastern part of it.