The 76th JSAP Autumn Meeting, 2015

Presentation information

Oral presentation

12 Organic Molecules and Bioelectronics » 12.2 Characterization and Materials Physics

[15p-2N-1~17] 12.2 Characterization and Materials Physics

6.6と12.2のコードシェアセッションあり

Tue. Sep 15, 2015 2:00 PM - 6:30 PM 2N (224-2(North))

座長:真島 豊(東工大),山田 洋一(筑波大)

4:00 PM - 4:15 PM

[15p-2N-9] Fundamental optical properties of lead iodide organic-inorganic layered perovskite with highly efficient exciton emission

〇Masanao Era1, Kazuhiro Ema2, Richard Phillips3 (1.Saga Univ., 2.Sophia Univ., 3.Cambridge Univ.)

Keywords:organic-inorganic layered perovskite,optical properies,exciton emission

We studies fundamental optical properties of PbI-based layered perovskite and the following results are demonstrate;
1, exciton band wiht high oscillator strength is located at 2.455 eV and the exciton has large binding energy of 260 meV.
2.emissions from singlet dominant Γ5 exciton and triplet dominant Γ2 exciton are observed in the PL measurement.
3. From PLE measurent, formation of exciton-plariton is confirmed.
4. From the temperature dependency of PL, unknown level involving to non-radiative decay exist at 3.33 eV,