2017年第78回応用物理学会秋季学術講演会

講演情報

一般セッション(口頭講演)

12 有機分子・バイオエレクトロニクス » 12.5 有機太陽電池

[6p-A501-1~21] 12.5 有機太陽電池

2017年9月6日(水) 13:30 〜 19:30 A501 (501)

曽我 哲夫(名工大)、豊田 太郎(電通大)、池上 和志(桐蔭横浜大)、米谷 真人(東大)

14:15 〜 14:30

[6p-A501-4] Effect of Mg-doped ZnO nanoparticles on H2O-oxidized ZnO nanorods-based perovskite solar cells

〇(D)Christian Ocson Pelicano1、Hisao Yanagi1 (1.Nara Institute of Science and Technology)

キーワード:ZnO nanorods, water oxidation, Mg-doped ZnO

Recently, perovskite solar cells (PSCs) have shown exceptional development and emerged as the top alternative for the Si-based photovoltaic technology [1]. Most efficient PSCs are based on compact or mesoporous TiO2 as electron transporting layer (ETL). However, high temperature sintering is usually required to synthesize TiO2 which hinders the application of PSCs in flexible substrates. Among metal oxides, ZnO is considered to be a possible alternative for TiO2 due to its comparable energy levels, higher electron mobility and low temperature processability. In our previous work, we demonstrated that ZnO nanorods (NRs) formed by low temperature H2O oxidation can be employed as ETL for PSCs [2]. Herein, we present the interfacial modification of H2O-oxidized ZnO NRs by Mg-doped ZnO (MZO) nanoparticles (NPs). This process will shift the conduction band minimum (CBM) of ZnO towards the LUMO of perovskite to facilitate easier electron injection from the active layer to ETL as shown in Fig. 1.
Firstly, Zn thin films were thermally evaporated on top of a ZnO compact layer. Fig. 2(a) shows ZnO NRs grown by H2O oxidation of Zn thin films at 90°C for 8h. MZO precursor solutions were prepared from the addition of Mg (CH3COO)2 · 4H2O and 0.25 M Zn(CH3COO)2 in methanol:H2O with Mg/(Mg+Zn) (molar ratio) of 5%, 10% and 20%. These solutions were then spin-coated on top of ZnO NRs and heated to 150°C for 1h. Fig. 1(b) shows that the surface of ZnO NRs became visibly rough due to the addition of 5% MZO NPs. All the samples have the same morphology with minimal variation in transparency. Finally, the ITO/ZnO NR-MZO NP samples will be utilized as ETL for PSCs with a configuration of ITO/ZnO-MZO/PCBM/CH3NH3PbI3/spiro-OMeTAD/Ag.