[15a-P8-1~31] 12.1 Fabrications and Structure Controls

[15a-P8-4] Inprovement of Carbazole Polymer Films/Inorganic Interface by Thiol-ene Reaction

〇Takaki Saito¹, Paul Advincula², Rigoberto Advincula², Kuniaki Tanaka¹, Hiroaki Usui¹ (1.Tokyo Univ. Agricul. & Technol., 2.Case Western Reserve Univ.)

Keywords:Vepor-Deposition Polymerization, Self-Assembled Monolayers, Polymer Thin Films

A poly(vinylcarbazole) thin film that was covalently tethered on a metal surface was obtained by vapor-deposition polymerization of N-vinylcarbazole on an Al surface that was modified with a self-assembled monolayer having thiol terminal unit. The tethering was achieved by thiol-ene reaction assisted by UV irradiation. This technique is promising for controlling the metal/organic interface.