[18p-PB3-1~95] 17 Nanocarbon Technology (Poster)

[18p-PB3-60] Transformation Mechanism of 5 to 6-Members Ring Structure in Nitrogen-doped Graphene Synthesis by Using Solution Plasma Process

〇Yukihiro Muta¹, Maria Antoaneta Bratescu², Nagahiro Saito^1,2,3 (1.Nagoya Univ., 2.Innovation for Future Society Inst., 3.Conjoint Research Lab. in Nagoya-Shinshu Univ.)

Keywords:Solution Plasma, Nitrogen-doped Graphene

From the result of the IRC and the vibration calculation by using Gaussian09 program, it was suggested that the reaction proceeds by starting expansion and contraction because of the balance of p-conjugated state around C-N connection collapses by obtaining a charge of N in imidazole.
In this study, it suggested that a compound having an imidazole ring is suitable as a synthesis source of high planarity nitrogen-doped graphene by using solution plasma.