[19a-432-1~12] 12.5 有機太陽電池

▲ [19a-432-12] Efficient Planar Perovskite Solar Cells via Interfacial Engineering with Anatase or Brookite TiO₂ Single-Crystalline Nanoparticles

〇(P)Md Shahiduzzaman^1,2、Sem Visal¹、Hiroto Ashikawa¹、Mizuki Kuniyoshi¹、Tetsuya Kaneko¹、Tetsuhiro Katsumata¹、Tetsuya Taima²、Satoru Iwamori¹、Masao Isomura¹、Koji Tomita¹ (1.Tokai Univ.、2.Kanazawa Univ.)

キーワード：Planar Perovskite Solar Cells, Interface Engineering, SP-TiO2/AT or BK SC-TiO2 NPs bilayer

The electron transport layer (ETL)/perovskite interface engineering plays a promising strategy to produce highly efficient planar heterojunction (PHJ) perovskite solar cells (PSCs). The deep trap states of ETL compact TiO₂ surface facilitates a large leakage current and recombination of electron-hole pairs. Interfacial modification of TiO₂ by a novel one-step hydrothermal processed single-crystalline anatase (AT) and/or brookite (BK) TiO₂ NPs with average diameter sizes about 6 and 30 nm, respectively, is applied as an ETL bilayer to enhance the separation of charges and suppress the recombination rate. Herein, a novel TiO₂/AT or BK TiO₂ NPs bilayer was introduced by comprising spray pyrolysis (SP) deposition and spin-coating (SC) technique, respectively, in PHJ PSCs. A SP-TiO₂/AT and BK SC-TiO₂ NPs bilayer-based PSCs are facilitated more efficient electron transport, charge extraction, and low interfacial recombination, and thus leads champion efficiencies up to 17.05% and 16.74%, respectively, by a significant decrease of J-V hysteresis, presenting almost 12% enhancement compared to TiO₂ single layer-based PSCs with PCE of 13.33%. The PHJ PSCs exhibited a spectral response that extended from the visible to the near-infrared region with a broad, flat absorption peak of intensity 80%-85% at approximately 380-750 nm. The higher IPCE value of the device with a bilayer in the visible-to-near-infrared wavelength region than those of the other devices suggests that the bilayer layer collect electrons more efficiently at the perovskite/TiO₂ edge because it successfully lowers the interfacial energy barrier. The outstanding performance of the bilayer ETL based device is attributed to the enhanced the content of photogenerated charge carrier sites and reduced the agglomeration and trapping at the SP-TiO₂ interface, as evident by PL analysis.