[19a-432-1~12] 12.5 有機太陽電池

▼ [19a-432-6] Co-additive Engineering of Lead free Perovskites Solar cells for Enhanced Photovoltaic Performance and Improved Stability

〇(D)Md Emrul Kayesh^1,2、Kiyoto Matsuishi²、Towhid H. Chowdhury¹、Ryuji Kaneko¹、Said Kazaoui³、Jae-Joon Lee⁴、Takeshi Noda¹、Ashraful Islam¹ (1.CEGREEM, NIMS、2.Univ. of Tsukuba、3.RCPV,AIST、4.Dongguk Univ.)

キーワード：Perovskite solar cells, Coadditive, Stability

Sn-based perovskite solar cells (PSCs) have attracted tremendous attention to the scientific community due to their low toxicity and superior optoelectronic properties in comparison to Pb-based perovskites. In spite of favorable photovoltaic properties, power conversion efficiency (PCE) of Sn-based PSCs remains far below as compared to Pb based system. The reasons for their inferior device performance are the facial tendency of oxidation from Sn²⁺ to Sn⁴⁺ which leads to unwanted p-type doping and to form films with lots of pin-holes. Here in this work, we find that the introduction of longer carbon chain as a coadditive in FASnI₃ precursor solution with SnF₂, significantly improves the stability of FASnI₃ films and increases the PL life time. From our Kenvin Probe Force Microscopy measurement, we observed that the addition of this coadditive minimized the contact potential difference between the grain interior and the grain boundaries, rendering the material more uniform under the solar cell operating condition. These remarkable enhancement of the FASnI₃ film boots the PCE of Sn-based PSCs from 2.5% to 6.95%. Moreover encapsulation the devices are highly stable under maximum power condition up to 100 h without any loss of efficiency. This study presents a simple and effective approach for enhancing performance and stability of Sn-based PSCs.