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[21p-438-11] Thermal Coefficient of Redox Potential in Co-Mn Prussian Blue Analogues
Keywords:Thermoelectric conversion, ion secondary battery
High thermal coefficient (α = ∂V/∂T) of redox potential (V) of electrodes is important in term of thermoelectric conversion. We evaluated α in a kind of solid solution of cobalt and manganese (NaxCo1-zMnz[Fe(CN)6]y ) as a function of z and discussed the dominant factors of α.