2:45 PM - 3:00 PM
▼ [20p-E319-5] Rapid-temperature-rising induced reduction of NiO film grown on Ni(111) surface
Keywords:oxidation, real-time XPS, Ni(111)
To clarify the potential of Ni surfaces as an alternative catalyst of Pt for exhaust gases of automobiles, the oxidation and reduction reaction kinetics on Ni(111) surfaces were investigated by X-ray photoelectron spectroscopy using synchrotron radiation (hv = 1100 eV) at BL23SU, SPring-8. By annealing at 700℃ under H2 atmosphere at PH2 = 9×10-4 Pa for 600 s, there were no traces of carbon, oxygen, sulfur, and chlorine contaminants within the detection limit.