[14a-A408-1~7] 12.3 Functional Materials and Novel Devices

[14a-A408-6] Selective Formation of Metal-Organic Frameworks under Vacuum Rabi Splitting

〇Kenji Hirai^1,2, Hiroto Ishikawa¹, James Hutchison³, Hiroshi Uji-i^1,4 (1.Hokkaido Univ., 2.JST PRESTO, 3.Melbourne Univ., 4.KU Leuven)

Keywords:Light-Matter Strong Coupling, Rabi Splitting, Metal-Organic Frameworks

Self-assembly of metal ions and organic ligands gives extended framework structures, so-called metal-organic frameworks (MOFs). Same combination of metal ions and organic ligands often yields different framework structures. In this work, we investigated the effects of vibrational strong coupling of solvent molecules in selective synthesis of metal–organic frameworks.