[28P02-001S] Boronic Acid-Catalyzed Site-selective Propargylation of Carbohydrates

○Daichi Sato¹, Naoyuki Shimada¹, Kazuishi Makino¹ (1. Department of Pharmaceutical Science, Kitasato University)

[28P02-002S] Synthesis of Macrocyclic Oligosaccharides by One-Pot Polyglycosylation of Thiogalactosyl Donors

○Gota Ishigami¹, Takehito Seki¹, Hidehisa Someya¹, Shin Aoki^1,2 (1. Faculty of Pharmaceutical Sciences, Tokyo University of Science, 2. Research Institute for Science and Technology, Tokyo University of Science)

[28P02-003S] Convergent production of chiral sulfoxide by using photo-racemization reaction

○Yuki Tanaka¹, Kosho Makino¹, Hidetsugu Tabata², Tetsuta Oshitari², Hideaki Natsugari³, Hideyo Takahashi¹ (1. Faculty of Pharmaceutical Sciences, Tokyo University of Science, 2. Faculty of Pharma Sciences, Teikyo University, 3. Faculty of Pharmaceutical Sciences, The University of Tokyo)

[28P02-004] Asymmetric metohxycarbonylation of allenes

○Taichi Kusakabe¹, Akane Mori¹, Kentaro Yoshiwaka¹, Kouta Mizushima¹, Keita Akada¹, Keisuke Takahashi¹, Hiroaki Sasai², Keisuke Kato¹ (1. Faculty of Pharmaceutical Sciences, Toho University, 2. The Institute of Scientific and Industrial Research (ISIR) Osaka University)

[28P02-005] Palladium-catalyzed N-benzylation of aminoisoquinolines in water

○Hidemasa Hikawa¹, Rie Tan¹, Aoi Tazawa¹, Shoko Kikkawa¹, Isao Azumaya¹ (1. Fac.Pharm.Sci., Toho Univ.)

[28P02-006S] Palladium-catalyzed dehydrogenation of benzyl alcohols for construction of imidazoquinolines in water

○Shogo Harada¹, Hidemasa Hikawa¹, Taku Nakayama¹, Shoko Kikkawa¹, Isao Azumaya¹ (1. Fac. Pharm. Sci., Toho Univ. )

[28P02-007] Palladium-Catalyzed Three-Component Coupling of Ynamides

○Hideaki Wakamatsu¹, Ayano Takahashi¹, Ayaka Ishii¹, Youhei Kikuchi¹, Madoka Sasaki¹, Yukako Saito¹, Yoshihiro Natori¹, Yuichi Yoshimura¹ (1. Fac. Pharm. Sci., Tohoku Med. Pharm. Univ.)

[28P02-008S] Synthesis of α,β-unsaturated ketone and substituted tetrahydroquinoline by ring-opening reaction using propargylazetidine

○Toya Kariya¹, Tsukasa Hiroknae¹, Misa Takata¹, Kenji Matsumoto¹, Masahiro Yoshida¹ (1. Faculty of Pharmaceutical Sciences, Tokushima Bunri University)

[28P02-009S] Development of catalytic asymmetric Nazarov Cyclization by boronic acid - axially chiral 2,2’-biphenol

○Ryuhei Hada¹, Miyu Oshiro¹, Kenji Sugimoto¹, Yuji Matsuya¹ (1. Faculty of Pharmaceutical Sciences, University of Toyama)

[28P02-010] Synthesis of cyclic guanidine via TM-HAT/RPC mechanism

Toshiya Ohuchi¹, Hiroki Koyama¹, ○Hiroki Shigehisa¹ (1. Faculty of Pharm, Musashino Univ.)

[28P02-011] Soluble Cross-Linked Polymer-Supported Dirhodium(II) Catalyst for Asymmetric Intramolecular C–H Insertion Reactions

Ryo Sato¹, Akira Kubota¹, ○Koji Takeda¹, Shigeki Matsunaga² (1. Faculty of Pharmaceutical Sciences, Hokkaido University of Science, 2. Faculty of Pharmaceutical Sciences, Hokkaido University)

[28P02-012S] One-pot γ-lactonization of homopropargyl alcohol via intramolecular ketene trapping

○Akihiro Hirata^1,2, Daichi Yamane¹, Haruna Tanaka¹, Yumiko Tamura¹, Tohru Nagamitsu¹, Masaki Ohtawa¹ (1. Sch.Pharm.Sci., Kitasato Univ, 2. Sch.Science.Sci., Kitasato Univ)

[28P02-013] Tandem Cyclization/Rearrangement Reaction of α-Diazoesters Triggered by DDQ Oxidation

Yasuyuki Hattori¹, ○Toshiki Akiyama¹, Hiroyuki Yamakoshi¹, Seiichi Nakamura¹ (1. Grad. Sch. Pharm. Sci., Nagoya City Univ.)

[28P02-014S] One-pot Synthesis of Halogenated Quinones from Phenolic Acids using Hypervalent Iodine(III) Reagent

○Kohei Ito¹, Hiromi Hamamoto¹ (1. Grad. Sch. Agric., Meijo Univ.)

[28P02-015S] Pd-Catalyzed Cyanation of Free Base Bromoporphyrins with NaCN

○Haruki Obata¹, Kotaro Ishigami¹, Satoshi Hayashi¹, Masahiro Noji¹, Toshikatsu Takanami¹ (1. Meiji Pharmaceutical Univ.)

[28P02-016S] Regioselective Trifluoromethylation of β-Silylporphyrins Using [(phen)(PPh₃)CuCF₃]

○Akari Okamoto¹, Ryoto Nabekura¹, Shiori Takeda¹, Satoshi Hayashi¹, Toshikatsu Takanami¹ (1. Meiji Pharmaceutical Univ.)

[28P02-017S] Alkoxymethylation of Silylmethylporphyrins via Electrochemical Oxidation

○Daisuke Ogiwara¹, Satoshi Hayashi¹, Toshikatsu Takanami¹ (1. Meiji Pharmaceutical Univ.)

[28P02-018S] Synthesis and Photophysical Properties of π-Extended Silylporphyrins

○Tetsuto Oishi¹, Satoshi Hayashi¹, Masahiro Noji¹, Toshikatsu Takanami¹ (1. Meiji Pharmaceutical Univ.)

[28P02-019S] Isomerization of Epoxides to Allylic Alcohols via Proton-Accelerated Lewis Acid Catalysis

○Misako Baba¹, Masahiro Noji¹, Toshikatsu Takanami¹ (1. Meiji Pharmaceutical Univ.)

[28P02-020S] Formation of sulfonium salts by interrupted Pummerer reaction and their reactivity

○Kai Yamamoto¹, Motoki Ito¹, Kazuhiro Higuchi¹, Shigeo Sugiyama¹ (1. Meiji Pharmaceutical University)

[28P02-021S] Synthesis of fluorine–containing phenylphenothiazine derivatives via aromatic nucleophilic substitution reaction

○Haruka Koyama¹, Kazuki Kodama², Kotaro Kikushima^1,2, Toshifumi Dohi^1,2 (1. Graduate School of Pharmacy., Ritsumeikan University., 2. College of Pharmaceutical Sciences., Ritsumeikan University.)

[28P02-022S] Selective hydroxylation using diaryliodonium salt with ortho-substituted phenyl group as dummy ligand

○Mina Saito¹, Kotaro Kikushima¹, Keina Komiyama², Yasuyuki Kita³, Toshifumi Dohi^1,3 (1. Grad. Sch. Pharm. Sci., Ritsumeikan Univ., 2. Grad. Sch. Life Sci., Ritsumeikan Univ., 3. Research Organization of Science and Technology, Ritsumeikan Univ.)

[28P02-023S] N-glycosylation of thio-glycoside derived from odorless thiol using hypervalent iodine(iii) reagent

Koji Morimoto^1,2, Kana Yanase¹, ○Kohei Matsubara¹, Yasuyuki Kita², Tetsuya Kajimoto^1,2 (1. College of Pharmaceutical Sciences, Ritsumeikan University, 2. Research Organization of Science and Technology, Ritsumeikan University.)

[28P02-024] Effect of magnesium ion on the radical-scavenging reaction of pterostilbene

○Ikuo Nakanishi¹, Yoshimi Shoji¹, Kei Ohkubo^1,2,3, Megumi Ueno¹, Kei Shimoda⁴, Toshihiko Ozawa⁵, Kiyoshi Fukuhara⁶, Hiroki Hamada⁷, Ken-ichiro Matsumoto¹ (1. Natl. Inst. Radiol. Sci., Natl. Inst. Quant. Radiol. Sci. Technol., 2. Inst. Adv. Co-Creation Stud., Osaka Univ., 3. Open Transdisciplinary Res. Initiatives, Osaka Univ., 4. Fac. Med., Oita Univ., 5. Nihon Pharm. Univ., 6. Sch. Pharm., Showa Univ., 7. Okayama Univ. of Sci.)

[28P02-025] Estimation of the formation mechanism of characteristic ladder compound using computational studies

Misaki Shinoda¹, ○Kosaku Tanaka, III¹, Yoshimitsu Hashimoto¹, Nobuyoshi Morita¹, Osamu Tamura¹ (1. Showa Pharmaceutical University)

[28P02-026] Mechanisms of the transesterifications between sulfonic acid and esters of other acids

○Yasushi Arakawa¹, Yukimi Arakawa¹ (1. Pharm. Sci., Hokuriku Univ.)

[28P02-L001] Hydroformylation of dialkenylamines and application to the synthesis of pyrrolizidine alkaloids

○Hisashi Masui^1,2, Sakura Niitsu², Mitsuru Shoji², Shinichiro Fuse¹, Takashi Takahashi^2,3 (1. Grad. Sch. Pharm. Sci., Nagoya Univ., 2. Grad. Sch. Pharm. Sci., Yokohama Univ. Pharm. , 3. Grad. Sch. Pharm. Sci., Kitasato Univ. Pharm. )

Session information

[28P02] 反応