The Japan Society of Applied Physics

[PS-6-06] NiO/GaN Composite Films as Photoelectrodes for Photoelectrochemical Hydrogen Generation and CO2 Reduction in NaCl Aqueous Electrolyte

Ching-Ying Sheu1, Shih-Sian Tu2, Shoou-Jinn Chang2 (1. National Tainan Girl’s Senior High School (Taiwan), 2. National Cheng Kung University (Taiwan))

https://doi.org/10.7567/SSDM.2023.PS-6-06

This study produced hydrogen gas and formic acid simultaneously through water photoelectrolysis and CO2 reduction, respectively, in the photoelectrochemical (PEC) reactions. The PEC reactions used GaN films with a NiO coating layer as photoelectrodes. The study explored the mechanism of the NiO layer functioning as a catalyst and/or protective layer. Additionally, it explored the effect of the thickness of the NiO layer on the performance of the GaN photoelectrodes. The study also noted that using CO2-containing NaCl aqueous solution as an electrolyte will open a window for using seawater for future PEC reactions.