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[PHp1-3L] Temperature Dependence of Photoluminescence Intensity in Y4Si2O7N2:Eu3+ Red Phosphors Synthesized in NH3 Atmosphere
Y4Si2O7N2:Eu3+, PL Temperature Dependence, Charge Transfer State, Activation Energy
The charge transfer state (CTS) energy of Y4Si2O7N2:Eu3+ phosphor was 3.61 eV which is almost the same as that of La2O2S:Eu3+. The activation energy from the CTS to 4f ground state is 0.24 eV The results suggest that Y4Si2O7N2:Eu3+ has several non-radiative transitions, due to crystal defects.