日本地球惑星科学連合2019年大会

講演情報

[E] ポスター発表

セッション記号 B (地球生命科学) » B-CG 地球生命科学複合領域・一般

[B-CG06] 地球惑星科学 生命圏フロンティアセッション

2019年5月28日(火) 17:15 〜 18:30 ポスター会場 (幕張メッセ国際展示場 8ホール)

コンビーナ:高野 淑識(海洋研究開発機構)、鈴木 庸平(東京大学大学院理学系研究科)、加藤 真悟(国立研究開発法人理化学研究所)、福士 圭介(金沢大学環日本海域環境研究センター)

[BCG06-P01] Dynamisms and characteristics of dissolved organic matter (DOM) in deep aquifer: A scope for deep biosphere

*浦井 暖史1,2高野 淑識2大河内 直彦2 (1.信州大学大学院総合医理工学研究科総合理工学専攻、2.国立研究開発法人海洋研究開発機構生物地球化学研究分野)

キーワード:高分子量溶存有機物、ステロール、炭素水素安定同位体比、深部帯水層、メタン生成

Dissolved organic matter (DOM) is generally derived from multiple sources and affected by complicated transformation and degradation reactions. In a general geochemical description of marine environments, high-molecular-weight DOM (HMW-DOM; >1 kDa) particularly represents a unique organic carbon pool, which is accompanied by considerable difference in the molecular and stable isotopic compositions from other organic components such as particulate organic matter (POM) and low-molecular-weight DOM (LMW-DOM; <1 kDa) (e.g., Benner et al., 1997).

To date, formation of DOM fraction and potential microbial interaction in deep aquifer have been particularly poorly understood on the context of prokaryotic ecology. We investigated the molecular composition of DOM fraction including LMW and HMW by an improved method (Urai et al., 2018). The filtered samples are tentatively defined by conventional size scales; macromolecular scale (100 mm >> 40 mm), POM (40 mm >> 0.6 mm), HMW-DOM(0.6 mm>>1kDa), and total-DOM (<0.6 mm). We also have a validation to distinguish the molecular signature between phototrophic primary producers (i.e., fossil molecules) and presently living benthic prokaryotes (i.e., modern molecules; cf. biological methanogenesis, Kaneko et al., 2014). We report a preliminary result of the feasibility study and discuss a perspective from the view of deep biosphere.


References:
Benner et al. Abundance, size distribution, and stable carbon and nitrogen isotopic compositions of marine organic matter isolated by tangential-flow ultrafiltration. Marine Chemistry 57, 243-263 (1997).

Kaneko et al. Quantitative analysis of coenzyme F430 in environmental samples: a new diagnostic tool for methanogenesis and anaerobic methane oxidation. Analytical Chemistry 86, 3633-3638 (2014).

Urai et al. Algal-derived 24-ethylcholesta-5, 22-dien-3β-ol (stigmasterol) is frequently found in high-molecular-weight dissolved organic matter (HMW-DOM) during summer in freshwater and brackish lakes. Geochemical Journal 52, e15-e20 (2018).