[A-OS17] Chemical and Biological Oceanography

[AOS17-P02] Chemical speciation of iron in the euphotic zone along the Kuroshio Current

*Mitsuhide Sato¹, Jun Nishioka², Kazuyuki Maki², Shigenobu Takeda¹ (1.Graduate School of Fisheries and Environmental Sciences, Nagasaki University, 2.Institute of Low Temperature Science, Hokkaido University)

Keywords:ligands, humic substances, iron, Kuroshio

The distributions of dissolved iron (DFe) and organic iron-binding ligands (FeL) in the Kuroshio Current and its neighboring waters were elucidated from four cross-sectional surveys from the eastern coast of Taiwan to Sagami Bay. The Kuroshio surface water was characterized by a high salinity, low concentration of DFe, high concentration of FeL, and low fluorescence of humic-like substances, in comparison to the neighboring waters. The neighboring waters of the Kuroshio can be categorized into two types: the East China Sea water and coastal water. The East China Sea water was found near the Okinawa Trough, and characterized by a steep vertical gradient of DFe concentration, almost as low as that in the Kuroshio within the surface mixed layer, but reached ~0.5 nM below the mixed layer. Coastal water was observed on the southern coast of Japan, and its DFe concentration was high throughout the upper 200 m. The concentration of FeL in the Kuroshio water was significantly higher in the surface (10 m) layer than in the subsurface layers. This suggests that humic-like substances, which are a major component of FeL in estuarine and deep waters, play a relatively minor role in the Kuroshio surface waters. Mixing with coastal waters can increase the concentration of bioavailable free ferric ions in the Kuroshio surface water in two ways, by increasing the DFe concentration and decreasing the FeL concentration.