日本地球惑星科学連合2022年大会

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[E] ポスター発表

セッション記号 A (大気水圏科学) » A-HW 水文・陸水・地下水学・水環境

[A-HW24] 流域圏生態系における物質輸送と循環:源流から沿岸海域まで

2022年6月1日(水) 11:00 〜 13:00 オンラインポスターZoom会場 (11) (Ch.11)

コンビーナ:安元 純(琉球大学 農学部)、コンビーナ:小林 政広(国立研究開発法人森林研究・整備機構 森林総合研究所)、奥田 昇(神戸大学)、コンビーナ:Paytan Adina(University of California Santa Cruz)、座長:安元 純(琉球大学 農学部)、奥田 昇(神戸大学)、小林 政広(国立研究開発法人森林研究・整備機構 森林総合研究所)

11:00 〜 13:00

[AHW24-P08] Pollution sources of groundwater contamination diagnosed by boron isotope composition in Okinawa, Yoron, and Tarama Islands, southern Japan

*ソウ カカン1、伊藤 湧人1、諸見里 結美1新城 竜一2、高田 良悟3安元 純4 (1.琉球大学大学院工学研究科物理地球科学コース、2.総合地球環境学研究所、3.琉球大学戦略研究プロジェクトセンター、4.琉球大学農学部農学部地域農業工学科)

キーワード:ホウ素、トレーサー、地下水汚染、琉球石灰岩

Groundwater is very important resources at the Ryukyu Limestone area of Ryukyu islands, southern Japan. On these islands, groundwater pollution such as an increase in the concentration of nitrate nitrogen has become apparent due to the increased human activity. In this study, Boron (B) concentration and B isotope composition are utilized as a tracer to demonstrate the pollution source in the agricultural environment. Manure and chemical fertilizer contain significant amount of B; it is leached by rainfall and migrate through the soil to contaminate the groundwater. In this study, we utilized the characteristic of B to reveal the pollution processes in the southern part of Okinawa Island, Tarama Island, and Yoron Island. We also collected precipitations at Ginowan City and fertilizers in the local areas as endmembers of mixing curves.
The B concentrations and δ11B values are 12-168 ppb and 19.5-38.1 ‰ in the southern part of Okinawa Island; 25-4247 ppb and 32.8-41.3 ‰ in Tarama Island; 20-26 ppb and 25.2-33.7 ‰ in Yoron Island. The mixing curve of precipitation and seawater represents the influence of seawater. In Tarama Island, the boundary of freshwater lens is clearly defined by sharp increases in B concentration in groundwater with δ11B values approaching to those of seawater. According to the characteristic of B, the groundwater of the southern part of Okinawa Island, Tarama Island, and Yoron Island can be reproduced by mixing precipitation with 0.6%, 0.8%, and 0.3% seawater. Two mixing curves between the least polluted groundwater and average δ11B values of manure (20 ‰) and chemical fertilizer (-5 ‰) in the southern part of Okinawa Island and Tarama Island are applicable to quantitative evaluation of contamination. In Yoron Island, the average δ11B values of manure and chemical fertilizer are 31‰ and -3‰, respectively, and our data indicate that Yoron groundwater is influenced by 0.1% of chemical fertilizers. These results demonstrate that B concentration and its isotope composition of groundwater can be useful tracers for contamination processes in the Ryukyu Limestone area.