[2B11-13] ポリマー・オリゴマー 3

[2B11] Synthesis and properties of star polymers with norbornene-alpha-olefin gradient copolymer arms using ansa-fluorenylamidodimethyltitanium-[Ph₃C][B(C₆F₅)₄] catalyst system

○袁 浩波¹、田中 亮¹、中山 祐正¹、塩野 毅¹ (1. 広島大学大学院先進理工系科学研究科応用化学専攻)

We attempted to synthesize star polymers with poly(norbornene-co-octene) gradient arms in one pot by using ansa-fluorenylamidodimethyltitanium-[Ph₃C][B(C₆F₅)₄]. The formation of the star polymers cores was investigated by adding a series of dinenes after the living copolymerization.