[2B11-13] Polymer, oligomer 3

[2B13] Synthesis of bio-based long-chain polyesters by tandem acyclic diene metathesis (ADMET) polymerization

○Mika Kojima ², Permpoom Chaijaroen¹, Yuichi Matsumoto¹, Kotohiro Nomura¹ (1. Dept. of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 2. Dept. of Chemistry, Faculty of Science, Tokyo Metropolitan University)

In this lecture, we wish to introduce one-pot synthesis of saturated polyester from bio-based monomers (nonconjugated dienes) by acyclic diene metathesis polymerization using ruthenium-carbene catalysts and subsequent hydrogenation.