2016年 第77回応用物理学会秋季学術講演会

講演情報

一般セッション(口頭講演)

12 有機分子・バイオエレクトロニクス » 12.5 有機太陽電池

[16p-A41-1~8] 12.5 有機太陽電池

2016年9月16日(金) 13:15 〜 15:30 A41 (国際会議室)

村田 英幸(北陸先端大)、米谷 真人(東大)

13:15 〜 13:30

[16p-A41-1] Study pertaining to spray deposited Cs2SnI6 thin films for perovskite solar cells

〇(P)Gaurav Kapil1、Takeshi Ohta2、Yuhei Ogomi2、Tsuguo Koyonagi2、Kenji Yoshino3、Qin Shen4、Taro Toyoda4、Takashi Minemoto6、Takurou N. Murakami5、Hiroshi Segawa1、Shuzi Hayase2 (1.University of Tokyo、2.Kyu. Inst. Tech.、3.Uni. Miya.、4.Uni. Elect.、5.Adv.Ind.Sc.&Tech.、6.Ritsu. Uni.)

キーワード:Cs2SnI6, Perovskite Solar Cells

Cs2SnI6 is expected to be a potential candidate for lead free perovskite solar cells [1]. Knowledge of the majority carrier in a photovoltaic material is an important issue for utilizing it effectively for solar cell application. Cs2SnI6 has been successfully incorporated as an efficient hole transport material for dye sensitized solar cell, indicating its p-type semiconductor behavior [2]. However, the nature of the majority carrier is still debatable as some of the reports claimed its n-type behavior only [3]. Apart from the nature of the material, the formation of pure, dense and thin films of desired thickness of Cs2SnI6 by solution processible method is difficult task to perform [3] due to its poor solubility in any solvent. Hence, in this work first time we fabricated pure thin films of Cs2SnI6 by spray coating method efficiently. Films were analyzed for the nature of carrier and important physical properties such as mobility, diffusion length and carrier life time.
References.
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B. Lee and M. G. Kanatzidis et.al, Jour. Am. Chem. Soc., 2014, 136, 15379-15385.
B. Saparov and D. B. Mitzi, Chem. Mater., 2016, 28, 2315-2322.