[22a-H116-1~6] 15.2 II-VI族結晶および多元系結晶

▲ [22a-H116-4] Enhanced photocatalytic performance under visible light irradiation due to controlled morphology evolution of ZnO nanostructure

〇サンダナクリシュナン ハリッシュ¹、ジャヤラム アーチャナ¹、マニ ナヴァニーザン¹、スルタイヤウダイヤ ポヌサミー²、チェラムス ムタミチェルバン²、ハヤカワ ヤスヒロ¹ (1.静岡大電子研、2.スリ・ラマサミー・メモリアル大学)

キーワード：ZnO nanostructures,photocatalytic performance,visible light irradiation

Zinc oxide (ZnO) nanostructures were synthesized and their photocatalytic activity was evaluated using methylene blue (MB) as a model pollutant. Ethylenediamine (EDA) was used as a passivating agent to control the morphology and size of the ZnO nanostructures. In the absence of EDA, agglomerated ZnO nanoparticles were obtained. The addition of EDA at varying concentrations considerably influenced the morphological size. The as-prepared samples were extensively characterized using various techniques. The morphology- and size-dependent photocatalytic degradation of MB was studied under visible light irradiation. Maximum degradation efficiency was
observed for ZnO nanoflakes; the MB-related absorbance peak completely disappeared after 15 min of irradiation. Furthermore, the effect of various photocatalytic reaction parameters, such as pH (3-12) of the solution, concentration of dye (5, 10, 15, and 20 ppm), and dosage of photocatalyst (25, 50, 75, and 100 mg/L), on the photodegradation of MB was investigated to determine the maximum degradation efficiency. The optimum values of solution pH, dye concentration, and photocatalyst dosage were 11, 10 ppm, and 75 mg/L, respectively.