[5p-PA2-1~29] 12.1 Fabrications and Structure Controls

[5p-PA2-21] Tethering of Organic Semiconductor/Metal Electrode Interface by Thiol-ene Reaction

〇Takaki Saito¹, Paul Advincula², Rigoberto Advincula², Kuniaki Tanaka¹, Hiroaki Usui¹ (1.Tokyo Univ. of Agricul. & Technol., 2.Case Western Reserve Univ.)

Keywords:Vapor Deposition Polymerization, Organic Semiconductor, Surface Chemistry

Vinylcarbazole monomers were deposited on the chemically modified Al surface, which was having a thiol terminated self-assembled monolayer. And the surface-tethered poly(vinylcarbazole) thin film was obtained by vapor-deposition polymerization using thiol-ene reaction. This technique is promising for controlling the metal/organic interface.