2017年第78回応用物理学会秋季学術講演会

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一般セッション(口頭講演)

6 薄膜・表面 » 6.2 カーボン系薄膜

[6p-A412-1~15] 6.2 カーボン系薄膜

2017年9月6日(水) 13:15 〜 17:30 A412 (412)

小山 和博(デンソー)、嘉数 誠(佐賀大)、鹿田 真一(関西学院大)

15:45 〜 16:00

[6p-A412-10] Growth and Characterization of Conductive Diamond Multilayers for Schottky Diodes

Alexandre FIORI1、Tokuyuki TERAJI1 (1.NIMS)

キーワード:diamond, conductive multilayer, Schottky diode

Recent progresses in diamond Schottky-barrier diodes (SBD) aimed to increase breakdown voltage and to minimize serial resistance. Therefore, serial resistance has been reduced by working on diode structures containing heavily boron-doped (p+) layers or conductive (p-type) substrates. However, highest breakdown voltages are still obtained on resistive conventional SBDs structures, based on insulating substrate without a p+-layer. We suppose that crystalline defects located inside p+-layer and at its interfaces initiate dislocations, which propagate throughout SBDs, and worsen breakdown voltage ability.
In this study, we fabricated highly crystalline conductive diamond multilayers by alternating thin boron-doped films with [B] ~ 1020 cm−3 (p+) and [B] ~ 1018 cm−3 (p). These p+p multilayers were used to build the conductive pathway of SBDs. Different B/C gas ratios have been employed to determine the effect of boron doping level on the crystallinity. Despite the variation of B/C gas ratios, doping levels in p+-layers remained unchanged. Boron incorporation saturated near the metal-semiconductor transition (~ 3×1020 cm−3). We made the hypothesis that incorporation saturation is correlated to a low density of dislocations in the layer. Therefore, we assume to increase charge carrier density in p+p multilayers, while maintaining dislocation density low. That property of p+p multilayer in SBDs has been appraised from reverse blocking voltage and forward current with respect to our previous results obtained on conventional SBDs.