2019年第66回応用物理学会春季学術講演会

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一般セッション(ポスター講演)

12 有機分子・バイオエレクトロニクス » 12.5 有機太陽電池

[10a-PB1-1~34] 12.5 有機太陽電池

2019年3月10日(日) 09:30 〜 11:30 PB1 (武道場)

09:30 〜 11:30

[10a-PB1-20] One-pot synthesis of D–p–D–p–D type holetransporting
materials for perovskite solar cells by sequential C–H (hetero)arylations

〇(M2)ChangChieh Ting1、KunMu Lee2、KuanMing Lu1、Ching-Yuan Liu1 (1.National Central Univ.、2.Chang Gung Univ.)

キーワード:Perovskite solar cell, Hole Transport Material

We report a step-saving new access to D–p–D–p–D type oligoaryls through one-pot sequential C–H (hetero)arylations. Conventionally, these oligomers were prepared by Stille or Suzuki coupling reactions that required prefunctionalization steps. The facilely synthesized linear oligomers were fabricated in perovskite-based solar devices as efficient hole transporters, exhibiting a power conversion efficiency of up to 15.4%.