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△ [10a-S222-5] Transistor characteristics of charge-transfer complexes of acceptors derived from birhodanines
Keywords:Organic Field-Effect Transitor, Charge-transfer complex
Recently, we have reported that birhodanine, 3,3'-dialkyl-5,5'-bithiazolidinyli dene-2,4,2',4'-tetrathiones (SS-R), is a n-channel transistor material with excellent air stability. In view of the strong acceptor ability, in the present work, we have attempted to prepare the charge-transfer complexes. A ferrocene complex of SS-Et as well as ferrocene and tetramethyltetrathiafulvalene complexes of the dicyano methylene derivative have been reported;these combinations afford mixed-stack structures.
The present work reports crystal structures of SS-Et and SS-Pr complexes of perylene, coronene, and pyrene. These cocrystals have mixed-stack columns, though the details depend on the alkyl chains and donors. Several cocrystals exhibit electron-transporting transistor properties, which are discussed in view of the calculations of the transfer integrals.
The present work reports crystal structures of SS-Et and SS-Pr complexes of perylene, coronene, and pyrene. These cocrystals have mixed-stack columns, though the details depend on the alkyl chains and donors. Several cocrystals exhibit electron-transporting transistor properties, which are discussed in view of the calculations of the transfer integrals.