[18p-Z15-1~15] 6.4 薄膜新材料

▼ [18p-Z15-13] The synthesis of high-entropy perovskite oxide epitaxial thin films using a pulsed laser deposition technique

〇(D)Kaidong Wang¹、Kazunori Nishio¹、Kurei Edamura¹、Yuki Sasahara¹、Ryo Nakayama¹、Ryota Shimizu^1,2、Taro Hitosugi¹ (1.Tokyo Tech、2.JST-PRESTO)

キーワード：High-entropy oxides, epitaxial thin films, perovskite

ABO₃ perovskite oxides exhibit excellent and diverse physical properties for applications in a variety of areas, such as solid oxide fuel cells, proton conductors, photocatalysts, dielectrics, ferroelectrics, and multiferroics. Recently, ABO₃ perovskite has been extended to high-entropy compositions to explore an unexpected functionality. In general, a single structural phase of high-entropy perovskite oxides (HEPOs) is formed by enhancing the configurational entropy of a multiple component solid solution through mixing a large number of cations. However, the synthesis of HEPOs is at a very early stage, and thus, the stabilization of the perovskite structure has yet to be well studied. Accordingly, we focused on the synthesis of HEPO epitaxial thin films, containing a variety of cations in A and B sites with more than 10 elements. As a result, we succeeded in the synthesis of a single phase of HEPO epitaxial thin films, which contains Ca, Sr, and Ba in A site and Si, Ti, Cr, Mn, Fe, Co, Ni, Ge, Zr, Sn, Ce, and Hf in B site, respectively.