2022年第83回応用物理学会秋季学術講演会

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12 有機分子・バイオエレクトロニクス » 12.3 機能材料・萌芽的デバイス

[21p-P18-1~40] 12.3 機能材料・萌芽的デバイス

2022年9月21日(水) 16:00 〜 18:00 P18 (体育館)

16:00 〜 18:00

[21p-P18-40] Influence of Reactant Gases on Ionomer’s Proton Conductivity on Quartz

〇(PC)Rahul Bhardwaj1、Isao Shitanda2、Yuki Nagao1 (1.JAIST、2.Tokyo Univ. of Sci.)

キーワード:Gases dependent H+ conductivity, Nafion thin-film, PEMFC

Ionomer thin film plays a crucial role as ionic conductor at cathode catalyst layer and strongly influences the performance of a PEMFC. The electrochemical performance can be limited by the transport of protons, electrons, or reactant gases (H2 and O2) to the catalyst sites. Since the ionomer film coating the carbon-supported Pt-based catalysts (Pt/C) is distributed in spatially heterogeneous manner at electrode, recently researchers are focusing on substrate dependent attribution of proton (H+) conductivity. However, the effect of reactant gases on ionomer H+ conductivity is barely reported. In this work we are investigating the influence of reactant gases on Nafion thin-film H+ conductivity at quartz using Pt IDEs.