[D203-3pm] 10. Organic Chemistry -Organometallic Compounds-

Fri. Mar 25, 2022 1:20 PM - 3:40 PM D203 (Online Meeting)

Chair: Kosuke Higashida, Yasunori Minami

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1:20 PM - 1:40 PM

[D203-3pm-01] A Boron-Transfer Mechanism Mediating the Thermally Induced Revival of Frustrated Carbene−Borane Pairs from their Shelf-Stable Adducts

^○Mahiro Sakuraba¹, Yoichi Hoshimoto¹, Jyunya Hasegawa², Sensuke Ogoshi¹ (1. Graduate School of Engineering, Osaka Univ. , 2. Institute for Catalysis, Hokkaido Univ.)

[Lang.] English

1:40 PM - 2:00 PM

[D203-3pm-02] Regiodivergent and Stereoselective Intermolecular [2+2] Cycloaddition of Amino-functionalized Alkenes and Allenes by Rare-Earth Catalysts

^○Wenxuan Xu^1,2, Xuefeng Cong¹, Kun An¹, Shaojie Lou¹, Zhenghua Li¹, Masayoshi Nishiura¹, Tetsuro Murahashi², Zhaomin Hou^1,2 (1. RIKEN, 2. Tokyo Institute of Technology)

[Lang.] English

2:00 PM - 2:20 PM

[D203-3pm-03] Advancement of a cooling system for solution XAS experiment and in situ local structure analysis of boryl copper species by XAS measurements

^○Yuta Uetake^1,2, Yu Ozawa³, Kazuki Matsumoto⁴, Tetsuo Honma⁵, Koji Kubota^3,6, Hajime Ito^3,6 (1. Grad. Sch. Eng., Osaka Univ., 2. ICS-OTRI, Osaka Univ., 3. Grad. Sch. Eng., Hokkaido Univ., 4. DFC Co., Ltd., 5. JASRI, 6. WPI-ICReDD, Hokkaido Univ.)

[Lang.] Japanese

2:20 PM - 2:40 PM

[D203-3pm-04] Nucleophilic Addition of Carboxylic Acids and Phenols toward Non-activated Alkynes Catalyzed by Gold-Zinc Bimetallic Complexes Including Imidazo[1,5-a]pyridine-3-ylidene Ligands

^○Vishal Kumar Rawat², Kosuke Higashida^1,2, Masaya Sawamura^1,2 (1. WPI-ICReDD, Hokkaido University, 2. Faculty of Science, Hokkaido University)

[Lang.] English

2:40 PM - 3:00 PM

[D203-3pm-05] Regio- and Diastereoselective [3 + 2] Annulation of Aliphatic Aldimines with Alkenes via beta-C(sp3)−H Activation by Scandium Catalysts

^○Xuefeng Cong¹, Masayoshi Nishiura¹, Zhaomin Hou¹ (1. RIKEN)

[Lang.] English

3:00 PM - 3:20 PM

[D203-3pm-06] Chromium-catalyzed syn-Stereoselective Ring-opening Arylation of 7-Oxabenzonorbornadienes

^○Kohei Nishi¹, Hayato Tsurugi¹, Kazushi Mashima¹ (1. Osaka Univ.)

[Lang.] English

3:20 PM - 3:40 PM

[D203-3pm-07] Yttrium-Catalyzed Reagioselective Alumination and Subsequent Functionalization of Benzylic C−H Bonds of 2-Alkylpyridines

^○Masanori Takimoto^1,2, Masayoshi Nishiura^1,2, Zhaomin Hou^1,2 (1. RIKEN CPR, 2. RIKEN CSRS)

[Lang.] Japanese

Session information

[D203-3pm] 10. Organic Chemistry -Organometallic Compounds-

[D203-3pm-01] A Boron-Transfer Mechanism Mediating the Thermally Induced Revival of Frustrated Carbene−Borane Pairs from their Shelf-Stable Adducts

[D203-3pm-02] Regiodivergent and Stereoselective Intermolecular [2+2] Cycloaddition of Amino-functionalized Alkenes and Allenes by Rare-Earth Catalysts

[D203-3pm-03] Advancement of a cooling system for solution XAS experiment and in situ local structure analysis of boryl copper species by XAS measurements

[D203-3pm-04] Nucleophilic Addition of Carboxylic Acids and Phenols toward Non-activated Alkynes Catalyzed by Gold-Zinc Bimetallic Complexes Including Imidazo[1,5-a]pyridine-3-ylidene Ligands

[D203-3pm-05] Regio- and Diastereoselective [3 + 2] Annulation of Aliphatic Aldimines with Alkenes via beta-C(sp3)−H Activation by Scandium Catalysts

[D203-3pm-06] Chromium-catalyzed syn-Stereoselective Ring-opening Arylation of 7-Oxabenzonorbornadienes

[D203-3pm-07] Yttrium-Catalyzed Reagioselective Alumination and Subsequent Functionalization of Benzylic C−H Bonds of 2-Alkylpyridines

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