[J402-4am] 09. Coordination Chemistry, Organometallic Chemistry

[J402-4am-04] Synthesis and structural analysis of a gold cluster Au₁₈S₂(SR)₁₂ (R = 2,4,6-C₆H₂ⁱPr₃CH₂) protected by bulky thiolate ligands

^○Taro Shigeta¹, Shinjiro Takano¹, Tatsuya Tsukuda^1,2 (1. Graduate School of Science, The Univ. of Tokyo, 2. ESICB, Kyoto Univ.)

[Lang.] English

Keywords:ligand-protected gold cluster, superatom, interlocked cage structure, single-crystal X-ray diffraction, density functional theory calculation