Academic Program [Oral A]

15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology- » Oral A

[K704-2vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Thu. Mar 23, 2023 4:10 PM - 6:40 PM K704 (K704, Lecture Hall Bldg. [7F])

Chair: Kenichi Michigami, Minami Odagi

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4:10 PM - 4:20 PM

[K704-2vn-01] Iodocyanation of enamides catalyzed by trispentafluorophenylborane (BCF)

^○Ikumi Furusawa¹, Takumi Suzuki, Takayoshi Arai¹ (1. Graduate School of Science, Chiba University)

[Lang.] Japanese

4:20 PM - 4:30 PM

[K704-2vn-02] Machine-Learning Prediction of Catalytic Activity in Dehydrative
Amidation

^○Taiki Nagano¹, Naoki Noto², Susumu Saito^2,3 (1. Nagoya University, 2. Integrated Research Consortium on Chemical Sciences, Nagoya University (IRCCS, Nagoya Univ.), 3. Graduate School of Science, Nagoya University (Grad. Sch. Sci., Nagoya Univ.))

[Lang.] Japanese

4:30 PM - 4:40 PM

[K704-2vn-03] Development of chiral Lewis acid catalysis self-repairable in water

^○Taku Kitanosono¹, Fangqiu Lu¹, Yasuhiro Yamashita¹, Shu Kobayashi¹ (1. The University of Tokyo)

[Lang.] Japanese

4:40 PM - 4:50 PM

[K704-2vn-04] Scalling-up study for flow manufacturing of drug precursors

^○Yosuke ASHIKARI¹, Kei MAEKAWA¹, Aiichiro NAGAKI¹ (1. Hokkaido University)

[Lang.] Japanese

4:50 PM - 5:00 PM

[K704-2vn-05] Development of modular synthesis of polyamines

^○Tokihiro Furuhashi¹, Shintaro Matsumoto¹, Satoshi Matsubara², Kei Murakami¹ (1. Kwansei Gakuin University, 2. Nagoya University)

[Lang.] Japanese

5:00 PM - 5:10 PM

[K704-2vn-06] Access to ortho-Hydroxyphenyl Ketimines via Imine Anion-Mediated Smiles Rearrangement

^○Shunki Jinno¹, Takahiro Senoo¹, Keiji Mori¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

5:10 PM - 5:20 PM

[K704-2vn-07] Boronic Acid-Catalyzed Peptide Bond Formation Using Amino Esters

^○Naoya Takahashi¹, Airi Takahashi², Naoyuki Shimada² (1. Kitasato University, 2. Nihon University)

[Lang.] Japanese

Break (5:20 PM - 5:30 PM)

5:30 PM - 5:40 PM

[K704-2vn-08] Development of a new synthetic method for boryldienes by 1,3-boron shift reaction of homoallenylboronates

^○RYOTA SAKAMOTO¹, Minami Odagi¹, Kazuo Nagasawa¹ (1. Tokyo University of Agriculture and Technology)

[Lang.] Japanese

5:40 PM - 5:50 PM

[K704-2vn-09] Electrophilic cyclization via boronate complex enables the synthesis of fluoromethyl-substituted cyclopropanes

^○Natsuki Oyama¹, Hajime Ito^1,2 (1. Graduate School of Engineering, Hokkaido University , 2. WPI-ICReDD, Hokkaido University)

[Lang.] Japanese

5:50 PM - 6:00 PM

[K704-2vn-10] Deoxygenative Geminal Silylboration of Amides

^○Koh Watanabe¹, Kazunori Nagao², Hirohisa Ohmiya² (1. Grad. Sch. Med. Sci., Kanazawa Univ., 2. ICR, Kyoto Univ.)

[Lang.] Japanese

6:00 PM - 6:10 PM

[K704-2vn-11] Highly Effective 1,3,2-Dioxaborolan-4-one Catalyst for Dehydrative Condensation of Carboxylic Acids with Amines

^○Qianchun HUANG¹, Shuhei Ohmura¹, Kazuaki Ishihara¹ (1. Nagoya University)

[Lang.] English

6:10 PM - 6:20 PM

[K704-2vn-12] Development of new fluorinated electron-withdrawing boronic esters facilitating mild deprotonation adjacent to the boron atoms

^○Taiki Maeda¹, Taisei Kamiyanagi², Kenichi Michigami¹, Mitsuhiro Ueda¹, Masato Ohashi¹ (1. Osaka Metropolitan University, 2. Osaka Prefecture University)

[Lang.] Japanese

6:20 PM - 6:30 PM

[K704-2vn-13] Transformation of Boracycles to Carbocycles Utilizing Photochemically-Generated Siloxycarbenes

^○Yu Matsuoka¹, Eriko Saito¹, Yamaguchi Kohei¹, Kento Ishida¹, Ryosuke Masuda¹, Hiroyuki Kusama¹ (1. Gakushuin Univ.)

[Lang.] Japanese

6:30 PM - 6:40 PM

[K704-2vn-14] Wittig Reactions Using Ambiphilic Phosphine-Borane Compounds

^○Seiya Endo¹, Kazuishi Hukuda¹, Nobuharu Iwasawa¹, Jun Takaya¹ (1. Tokyo Institute of Technology)

[Lang.] Japanese

Session information

[K704-2vn] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

[K704-2vn-01] Iodocyanation of enamides catalyzed by trispentafluorophenylborane (BCF)

[K704-2vn-02] Machine-Learning Prediction of Catalytic Activity in Dehydrative
Amidation

[K704-2vn-03] Development of chiral Lewis acid catalysis self-repairable in water

[K704-2vn-04] Scalling-up study for flow manufacturing of drug precursors

[K704-2vn-05] Development of modular synthesis of polyamines

[K704-2vn-06] Access to ortho-Hydroxyphenyl Ketimines via Imine Anion-Mediated Smiles Rearrangement

[K704-2vn-07] Boronic Acid-Catalyzed Peptide Bond Formation Using Amino Esters

[K704-2vn-08] Development of a new synthetic method for boryldienes by 1,3-boron shift reaction of homoallenylboronates

[K704-2vn-09] Electrophilic cyclization via boronate complex enables the synthesis of fluoromethyl-substituted cyclopropanes

[K704-2vn-10] Deoxygenative Geminal Silylboration of Amides

[K704-2vn-11] Highly Effective 1,3,2-Dioxaborolan-4-one Catalyst for Dehydrative Condensation of Carboxylic Acids with Amines

[K704-2vn-12] Development of new fluorinated electron-withdrawing boronic esters facilitating mild deprotonation adjacent to the boron atoms

[K704-2vn-13] Transformation of Boracycles to Carbocycles Utilizing Photochemically-Generated Siloxycarbenes

[K704-2vn-14] Wittig Reactions Using Ambiphilic Phosphine-Borane Compounds

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